18673-13-7

Basic information

• Product Name: methyl 3-ethylsulfanylpropanoate
• Synonyms: methyl 3-ethylsulfanylpropanoate;METHYL 3-(ETHYLTHIO)-PROPIONATE;HKZAEFYOTHDMNN-UHFFFAOYSA-N
• CAS NO: 18673-13-7
• Molecular Formula: C₆H₁₂O₂S
• Molecular Weight: 148.22
• Mol File: 18673-13-7.mol
• Article Data: 8

Chemical Properties

• Boiling Point: 200.5°Cat760mmHg
• Flash Point: 81°C
• Appearance: /
• Density: 1.022g/cm³
• Vapor Pressure: 0.324mmHg at 25°C
• Refractive Index: 1.458
• CAS DataBase Reference: methyl 3-ethylsulfanylpropanoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 3-ethylsulfanylpropanoate(18673-13-7)
• EPA Substance Registry System: methyl 3-ethylsulfanylpropanoate(18673-13-7)

Safety Data

• Hazardous Substances Data: 18673-13-7(Hazardous Substances Data)

Usage

InChI:InChI=1/C6H12O2S/c1-3-9-5-4-6(7)8-2/h3-5H2,1-2H3

Upstream product

• 67-56-1 methanol 
• 463-51-4 Ketene 
• 1708-73-2 chloromethyl ethyl sulfide 
• 21071-39-6 S-ethyl thioformate 
• 292638-85-8 acrylic acid methyl ester 
• 512-85-6 ascaridole 
• 75-08-1 ethanethiol 
• 3395-91-3 Methyl 3-bromopropionate 
• 1071-37-0 2-ethylisothiourea hydrobromide 
• 100-46-9 benzylamine 
• 100-85-6 N-benzyl-trimethylammonium hydroxide 

Downstream Products

• 89211-36-9 3-(ethylsulfonyl)propanoic acid 
• 111-17-1 4-thiaheptane-1,7-dioic acid 
• 352-93-2 diethyl sulphide 
• 99116-15-1 3-ethanesulfonyl-propionic acid methyl ester 
• 616-45-5 2-pyrrolidinon 
• 80096-39-5 N-benzyl 3-ethylthiopropionamide 

Relevant articles and documents

Thia-Michael addition using cheap and odorless S-alkylisothiouronium salts as thiol equivalents in water

S-Alkylisothiouronium salt has been found to be a non-toxic, odorless and simply operational alternative of thiol for the thia-Michael addition with electron-deficient olefins. The reactions were carried out under alkaline conditions in water at room temperature within 5-20 minutes to afford the expected products in good to excellent yields. Georg Thieme Verlag Stuttgart.

Borax as an efficient metal-free catalyst for hetero-Michael reactions in an aqueous medium

Borax, a naturally occurring material, very efficiently catalyzed the conjugate addition of thiols, dithiols and amines to α,β-unsaturated ketones, nitriles, amides, aldehydes and esters in an aqueous medium to afford the corresponding Michael adducts in good yields at room temperature. Recycling of the catalyst and scaling up of the reactions are important attributes of this catalysis. The reactions of thiols and dithiols were relatively more facile than those of the corresponding amines. Wiley-VCH Verlag GmbH & Co. KGaA, 2007.

CsF-Celite, an efficient solid state reagent for the syntheses of thioesters and thioethers

Coupling reactions of a number of aliphatic, aromatic, and heterocyclic compounds bearing an acidic hydrogen atom attached to sulfur, with alkyl, acyl, benzyl, or benzoyl halides in acetonitrile with cesium fluoride-Celite are described. This procedure is convenient, efficient, and practical for the preparation of thioethers and thioesters. Springer-Verlag 2005.