1868-00-4

Basic information

• Product Name: 3,3'-BIS(TRIFLUOROMETHYL)BENZOPHENONE
• Synonyms: LABOTEST-BB LT00159871;3,3'-BIS(TRIFLUOROMETHYL)BENZOPHENONE;3,3'-DI(TRIFLUOROMETHYL)BENZOPHENONE;3,3'-BIS(TRIFLUOROMETHYL)BENZOPHENONE, 9 8%;3,3'-Bis(trifluoromethyl)benzophenone 98%;3,3'-bis(trifluoromethyl),benzophenone;Bis[3-(trifluoromethyl)phenyl] ketone;Bis[3-(trifluoromethyl)phenyl]methanone
• CAS NO: 1868-00-4
• Molecular Formula: C₁₅H₈F₆O
• Molecular Weight: 318.21
• EINECS: -0
• Product Categories: Fluorine series
• Mol File: 1868-00-4.mol
• Article Data: 10

Chemical Properties

• Melting Point: 100-102 °C(lit.)
• Boiling Point: 328.6 °C at 760 mmHg
• Flash Point: 126 °C
• Appearance: yellow crystal powder
• Density: 1.3935 (estimate)
• Storage Temp.: Sealed in dry,Room Temperature
• Solubility: Chloroform (Slightly), Methanol (Slightly)
• BRN: 2297993
• CAS DataBase Reference: 3,3'-BIS(TRIFLUOROMETHYL)BENZOPHENONE(CAS DataBase Reference)
• NIST Chemistry Reference: 3,3'-BIS(TRIFLUOROMETHYL)BENZOPHENONE(1868-00-4)
• EPA Substance Registry System: 3,3'-BIS(TRIFLUOROMETHYL)BENZOPHENONE(1868-00-4)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-37/39
• WGK Germany: 3
• HazardClass: IRRITANT
• Hazardous Substances Data: 1868-00-4(Hazardous Substances Data)

Usage

Chemical Properties

yellow crystal powde

Upstream product

• 5325-94-0 N-Ethoxycarbonylpiperidine 
• 368-49-0 3-(trifluoromethyl)phenyllithium 
• 401-78-5 3-bromo-1-trifluoromethylbenzene 
• 368-77-4 3-trifluoromethylbenzonitrile 
• 75-61-6 dibromodifluoromethane 
• 434-45-7 2,2,2-Trifluoroacetophenone 
• 541-41-3 chloroformic acid ethyl ester 
• 199465-55-9 3-(trifluoromethyl)phenylzinc bromide 
• 79-37-8 oxalyl dichloride 
• 121899-80-7 tris(3-trifluoro-methylphenyl)bismuthane 
• 1179318-32-1 C₂₁H₁₂F₉In 
• 454-89-7 3-Trifluoromethylbenzaldehyde 
• 1598-89-6 3,3'-bis(trifluoromethyl)benzhydrol 
• 124-38-9 carbon dioxide 

Downstream Products

• 128190-78-3 1-(bis-(3-(trifluoromethyl)phenyl)methylene)-1H-cyclopropa{b}naphthalene 
• 3174-48-9 p-methylphenoxyl radical 
• 135547-62-5 5,5'-bistrifluoromethyl-3,3'-dinitro benzophenone 
• 120553-12-0 3,3-bis[3-(trifluoromethyl)phenyl]-2-propenal 
• 4660-85-9 6,6-{3-(trifluoromethyl)phenyl}fulvene 
• 462093-57-8 ethyl 3,3-bis[3-(trifluoromethyl)phenyl]acrylate 

Relevant articles and documents

Photo-induced phosphorus radical involved semipinacol rearrangement reaction: Highly synthesis of γ-oxo-phosphonates

Hydroxyphosphoric acids display the unique biological activities, and they have some attractive prospects as clinical drug moleculars. Herein, a new approach for the synthesis of γ-oxo-phosphonates (the precursor of hydroxyphosphoric acid) has been established through the semipinacol rearrangement tactic involved the photo-induced phosphorus radical process. Most important, this transformation is avoid of the external oxidants, and occurs very well under the sunlight irradiation, meanwhile the γ-oxo-phosphonate was easily derivatized to obtain γ-hydroxyphosphoric acid, thus highlights the synthesis value of this method.

Oxalyl chloride as carbonyl synthon in Pd-catalyzed carbonylations of triarylbismuth and triarylindium organometallic nucleophiles

Oxalyl chloride has been demonstrated to function as C1 carbonyl synthon in the carbonylations of triarylbismuth and triarylindium nucleophiles under palladium-catalyzed conditions. All the three aryl groups from both bismuth and indium reagents participated in carbonylative couplings to afford the corresponding functionalized ketones in high yields. This study also disclosed a novel utilization of oxalyl chloride as facile alternative source of CO for carbonylations under palladium catalysis.

Dications of fluorenylidenes. The relationship between redox potentials and antiaromaticity for meta- and para-substituted diphenylmethylidenefluorenes

Electrochemical oxidation of meta-substituted diphenylmethylidenefluorenes (3a-g) results in the formation of fluorenylidene dications that are shown to be antiaromatic through calculation of the nucleus independent chemical shift (NICS) for the 5- and 6-