187732-06-5Relevant articles and documents
Synthesis of methyl O-α-D-mannosyl-(1→4)-[(3-O-methyl-α-D-mannosyl) -(1→4)-]n3-O-methyl-α-D-mannosides (n = 0, 1, and 2) via dehydrative glycosylation
Hirooka, Motoko,Terayama, Megumi,Mitani, Emi,Koto, Shinkiti,Miura, Asako,Chiba, Kayo,Takabatake, Ayano,Tashiro, Takako
, p. 1301 - 1309 (2002)
Methyl O-α-D-mannopyranosyl-(1→4)-[(3-O-methyl-α-D-mannopyranosyl -(1→4)-]n3-O-methyl-α-D-mannopyra-nosides (n = 0, 1, and 2), the lowest homologs related to the 3-O-methylmannose polysaccharides (MMP) from Mycobacterium smegmatis, were synthesized via dehydrative glycosylation reactions. The reagent systems, composed of p-nitrobenzenesulfonyl chloride, silver trifluoromethanesulfonate, and triethylamine, of p-nitrobenzenesulfonyl chloride, silver trifluoromethanesulfonate, and 1, 8-diazabicyclo[5.4.0]undec-7-ene, and of trimethylsilyl trifuloromethanesulfonate and pyridine were useful.
Synthesis of a hexasaccharide acceptor corresponding to the reducing terminus of mycobacterial 3-O-methylmannose polysaccharide (MMP)
Liao, Wensheng,Lu, Depei
, p. 171 - 182 (2007/10/03)
The title compound methyl O-(2,6-di-O-benzyl-3-O-methyl-α-D-mannopyranosyl)-[( 1 → 4)-O-(2,6-di-O-benzyl-3-O-methyl-α-D-mannopyranosyl)]4-(1 → 4)-2,6-di-O-benzyl-3-O-methyl-α-D mannopyranoside (2) was synthesized in a blockwise manner, employin