187732-08-7

Upstream product

• 187732-06-5 allyl 4,6-O-benzylidene-3-O-methyl-α-D-mannopyranoside 
• 187732-04-3 allyl 3-O-methyl-α-D-mannopyranoside 
• 41308-76-3 allyl α-D-mannopyranoside 
• 155836-00-3 allyl 4,6-O-benzylidene-α-D-mannopyranoside 
• 100-39-0 benzyl bromide 
• 931098-45-2 (6-allyloxy-5-benzyloxy-2-benzyloxymethyl-4-methoxy-tetrahydro-pyran-3-yloxy)-trimethyl-silane 
• 194594-69-9 6-allyloxy-7-benzyloxy-8-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxine 
• 187732-07-6 allyl 2-O-benzyl-4,6-O-benzylidene-3-O-methyl-α-D-mannopyranoside 
• 1056479-53-8 allyl-4,6-O-benzylidene-2,3-di-O-hydroxy-D-mannopyranoside 
• 182212-07-3 α,β-O-allyl-D-mannopyranoside 
• 530-26-7 D-Mannose 

Downstream Products

• 187732-19-0 allyl 4-acetyl-2,6-dibenzyl-3-methyl-α-D-mannopyranosyl-(1->4)-2,6-dibenzyl-3-methyl-α-D-mannopyranoside 
• 194594-79-1 allyl 2,3,4,6-tetrabenzyl-α-D-mannopyranosyl-(1->4)-2,6-dibenzyl-3-methyl-α-D-mannopyranoside 
• 187732-09-8 allyl 4-O-acetyl-2,6-di-O-benzyl-3-O-methyl-α-D-mannopyranoside 
• 74426-45-2 2,3,4,6-tetra(p-chlorobenzyl)-α-D-mannopyranosyl-(1->1)-2,3,4,6-tetra(p-chlorobenzyl)-α-D-mannopyranoside 
• 931098-45-2 (6-allyloxy-5-benzyloxy-2-benzyloxymethyl-4-methoxy-tetrahydro-pyran-3-yloxy)-trimethyl-silane 
• 931098-46-3 benzoic acid 6-allyloxy-5-benzyloxy-2-benzyloxymethyl-4-methoxy-tetrahydro-pyran-3-yl ester 
• 187732-24-7 methyl 2,6-dibenzyl-3-methyl-α-D-mannopyranosyl-(1->4)-2,6-dibenzyl-3-methyl-α-D-mannopyranoside 
• 187732-23-6 methyl 4-acetyl-2,6-dibenzyl-3-methyl-α-D-mannopyranosyl-(1->4)-2,6-dibenzyl-3-methyl-α-D-mannopyranoside 
• 461658-99-1 methyl 2,3,4,6-tetrabenzyl-α-D-mannopyranosyl-(1->4)-2,6-dibenzyl-3-methyl-α-D-mannopyranosyl-(1->4)-2,6-dibenzyl-3-methyl-α-D-mannopyranoside 
• 461659-00-7 methyl 2,3,4,6-tetra(p-chlorobenzyl)-α-D-mannopyranosyl-(1->4)-2,6-dibenzyl-3-methyl-α-D-mannopyranosyl-(1->4)-2,6-dibenzyl-3-methyl-α-D-mannopyranoside 
• 194594-71-3 (2R,3R,4S,5S,6R)-6-((2R,3R,4S,5S,6S)-6-Allyloxy-5-benzyloxy-2-benzyloxymethyl-4-methoxy-tetrahydro-pyran-3-yloxy)-5-benzyloxy-2-benzyloxymethyl-4-methoxy-tetrahydro-pyran-3-ol 
• 931098-49-6 benzoic acid 6-(6-allyloxy-5-benzyloxy-2-benzyloxymethyl-4-methoxy-tetrahydro-pyran-3-yloxy)-5-benzyloxy-2-benzyloxymethyl-4-methoxy-tetrahydro-pyran-3-yl ester 

Relevant academic research and scientific papers

Synthetic 3-O-methylmannose-containing polysaccharides (sMMPs): Design and synthesis

With the hope of mimicking the chemical and biological properties of natural 3-O-methylmannose-containing polysaccharides (MMPs), synthetic 3-O-methylmannose-containing polysaccharides (sMMPs) were designed and synthesized in a convergent manner. With lit

Synthesis of methyl O-α-D-mannosyl-(1→4)-[(3-O-methyl-α-D-mannosyl) -(1→4)-]n3-O-methyl-α-D-mannosides (n = 0, 1, and 2) via dehydrative glycosylation

Methyl O-α-D-mannopyranosyl-(1→4)-[(3-O-methyl-α-D-mannopyranosyl -(1→4)-]n3-O-methyl-α-D-mannopyra-nosides (n = 0, 1, and 2), the lowest homologs related to the 3-O-methylmannose polysaccharides (MMP) from Mycobacterium smegmatis, were synthesized via dehydrative glycosylation reactions. The reagent systems, composed of p-nitrobenzenesulfonyl chloride, silver trifluoromethanesulfonate, and triethylamine, of p-nitrobenzenesulfonyl chloride, silver trifluoromethanesulfonate, and 1, 8-diazabicyclo[5.4.0]undec-7-ene, and of trimethylsilyl trifuloromethanesulfonate and pyridine were useful.

Synthesis of a hexasaccharide acceptor corresponding to the reducing terminus of mycobacterial 3-O-methylmannose polysaccharide (MMP)

The title compound methyl O-(2,6-di-O-benzyl-3-O-methyl-α-D-mannopyranosyl)-[( 1 → 4)-O-(2,6-di-O-benzyl-3-O-methyl-α-D-mannopyranosyl)]4-(1 → 4)-2,6-di-O-benzyl-3-O-methyl-α-D mannopyranoside (2) was synthesized in a blockwise manner, employin