187732-19-0

Basic information

• Product Name: allyl 4-acetyl-2,6-dibenzyl-3-methyl-α-D-mannopyranosyl-(1->4)-2,6-dibenzyl-3-methyl-α-D-mannopyranoside
• Synonyms: allyl 4-acetyl-2,6-dibenzyl-3-methyl-α-D-mannopyranosyl-(1->4)-2,6-dibenzyl-3-methyl-α-D-mannopyranoside
• CAS NO: 187732-19-0
• Molecular Weight: 812.954
• Mol File: 187732-19-0.mol

Chemical Properties

• CAS DataBase Reference: allyl 4-acetyl-2,6-dibenzyl-3-methyl-α-D-mannopyranosyl-(1->4)-2,6-dibenzyl-3-methyl-α-D-mannopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: allyl 4-acetyl-2,6-dibenzyl-3-methyl-α-D-mannopyranosyl-(1->4)-2,6-dibenzyl-3-methyl-α-D-mannopyranoside(187732-19-0)
• EPA Substance Registry System: allyl 4-acetyl-2,6-dibenzyl-3-methyl-α-D-mannopyranosyl-(1->4)-2,6-dibenzyl-3-methyl-α-D-mannopyranoside(187732-19-0)

Safety Data

• Hazardous Substances Data: 187732-19-0(Hazardous Substances Data)

Upstream product

• 187732-08-7 allyl 2,6-dibenzyl-3-methyl-α-D-mannopyranoside 
• 187732-11-2 Acetic acid (2R,3R,4S,5S,6R)-5-benzyloxy-2-benzyloxymethyl-4-methoxy-6-(2,2,2-trichloro-acetimidoyloxy)-tetrahydro-pyran-3-yl ester 
• 194594-70-2 1,4-di-O-acetyl-2,6-di-O-benzyl-3-O-methyl-α-D-mannopyranose 
• 100-39-0 benzyl bromide 
• 187732-06-5 allyl 4,6-O-benzylidene-3-O-methyl-α-D-mannopyranoside 
• 41308-76-3 allyl α-D-mannopyranoside 
• 187732-04-3 allyl 3-O-methyl-α-D-mannopyranoside 
• 187732-07-6 allyl 2-O-benzyl-4,6-O-benzylidene-3-O-methyl-α-D-mannopyranoside 
• 155836-00-3 allyl 4,6-O-benzylidene-α-D-mannopyranoside 

Downstream Products

• 194594-71-3 (2R,3R,4S,5S,6R)-6-((2R,3R,4S,5S,6S)-6-Allyloxy-5-benzyloxy-2-benzyloxymethyl-4-methoxy-tetrahydro-pyran-3-yloxy)-5-benzyloxy-2-benzyloxymethyl-4-methoxy-tetrahydro-pyran-3-ol 

Relevant articles and documents

Synthesis of methyl O-α-D-mannosyl-(1→4)-[(3-O-methyl-α-D-mannosyl) -(1→4)-]n3-O-methyl-α-D-mannosides (n = 0, 1, and 2) via dehydrative glycosylation

Methyl O-α-D-mannopyranosyl-(1→4)-[(3-O-methyl-α-D-mannopyranosyl -(1→4)-]n3-O-methyl-α-D-mannopyra-nosides (n = 0, 1, and 2), the lowest homologs related to the 3-O-methylmannose polysaccharides (MMP) from Mycobacterium smegmatis, were synthesized via dehydrative glycosylation reactions. The reagent systems, composed of p-nitrobenzenesulfonyl chloride, silver trifluoromethanesulfonate, and triethylamine, of p-nitrobenzenesulfonyl chloride, silver trifluoromethanesulfonate, and 1, 8-diazabicyclo[5.4.0]undec-7-ene, and of trimethylsilyl trifuloromethanesulfonate and pyridine were useful.

Synthesis of a tetra-and a hexasaccharide donor corresponding to the non-reducing termini of mycobacterial 3-O-methylmannose polysaccharide (MMP)

The blockwise synthesis of the title compounds, namely the tetra-and the hexasaccharide trichloroacetimidates (20) and (23), is described. Both acetates and imidates were employed as glycosyl donors in most of the coupling reactions. As nearly all of the

Synthesis of a hexasaccharide acceptor corresponding to the reducing terminus of mycobacterial 3-O-methylmannose polysaccharide (MMP)

The title compound methyl O-(2,6-di-O-benzyl-3-O-methyl-α-D-mannopyranosyl)-[( 1 → 4)-O-(2,6-di-O-benzyl-3-O-methyl-α-D-mannopyranosyl)]4-(1 → 4)-2,6-di-O-benzyl-3-O-methyl-α-D mannopyranoside (2) was synthesized in a blockwise manner, employin