18781-55-0Relevant articles and documents
N-indolyltriethylborate: A useful reagent for synthesis of C3-quaternary indolenines
Lin, Aijun,Yang, Jiong,Hashim, Mohamed
supporting information, p. 1950 - 1953 (2013/06/04)
N-Indolyltriethylborate was found to be a useful reagent for dearomatizing C3-alkylation of 3-substituted indoles with both activated and nonactivated alkyl halides to give C3-quaternary indolenines, pyrroloindolines, furoindoline, and hexahydropyridoindoline under mild reaction conditions. The utility of these reagents was demonstrated in the syntheses of a pyrroloindoline-4- cholestene hybrid and debromoflustramine B.
Palladium catalyzed decarboxylative rearrangement of N-alloc indoles
Chen, Jun,Cook, Matthew J.
supporting information, p. 1088 - 1091 (2013/04/10)
A highly efficient palladium catalyzed decarboxylative allylic rearrangement of alloc indoles has been developed. This can also be combined with a Suzuki-Miyaura cross-coupling reaction in a single pot transformation. Substituted alloc groups and benzylic variants have also been demonstrated alongside promising initial results on the enantioselective variant.
