1879-55-6Relevant articles and documents
Iron(II) and Copper(I) Control the Total Regioselectivity in the Hydrobromination of Alkenes
Cruz, Daniel A.,Sinka, Victoria,De Armas, Pedro,Steingruber, Hugo Sebastian,Fernández, Israel,Martín, Víctor S.,Miranda, Pedro O.,Padrón, Juan I.
supporting information, p. 6105 - 6109 (2021/08/18)
A new method that allows the complete control of the regioselectivity of the hydrobromination reaction of alkenes is described. Herein, we report a radical procedure with TMSBr and oxygen as common reagents, where the formation of the anti-Markovnikov product occurs in the presence of parts per million amounts of the Cu(I) species and the formation of the Markovnikov product occurs in the presence of 30 mol % iron(II) bromide. Density functional theory calculations combined with Fukui's radical susceptibilities support the obtained results.
Iron-catalyzed decarboxylative methylation of α,β-unsaturated acids under ligand-free conditions
Rong, Guangwei,Liu, Defu,Lu, Linhua,Yan, Hong,Zheng, Yang,Chen, Jie,Mao, Jincheng
, p. 5033 - 5037 (2014/12/10)
It is the first time to find that iron-catalyzed decarboxylative methylation of α,β-unsaturated acids could be performed in the absence of any ligands. During the reaction, the configuration of the double bond could be retained. It is noteworthy that di-t
Iron-catalyzed decarboxylative methylation of α,β-unsaturated acids under ligand-free conditions
Rong, Guangwei,Liu, Defu,Lu, Linhua,Yan, Hong,Zheng, Yang,Chen, Jie,Mao, Jincheng
, p. 5033 - 5037 (2014/07/08)
It is the first time to find that iron-catalyzed decarboxylative methylation of α,β-unsaturated acids could be performed in the absence of any ligands. During the reaction, the configuration of the double bond could be retained. It is noteworthy that di-t
