187986-23-8

Basic information

• Product Name: (4R,5S,6R)-4-Dimethoxymethyl-5-isopropyl-2-methyl-6-trimethylsilanyloxy-cyclohex-2-enone
• Synonyms: (4R,5S,6R)-4-Dimethoxymethyl-5-isopropyl-2-methyl-6-trimethylsilanyloxy-cyclohex-2-enone
• CAS NO: 187986-23-8
• Molecular Weight: 314.497
• Mol File: 187986-23-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (4R,5S,6R)-4-Dimethoxymethyl-5-isopropyl-2-methyl-6-trimethylsilanyloxy-cyclohex-2-enone(CAS DataBase Reference)
• NIST Chemistry Reference: (4R,5S,6R)-4-Dimethoxymethyl-5-isopropyl-2-methyl-6-trimethylsilanyloxy-cyclohex-2-enone(187986-23-8)
• EPA Substance Registry System: (4R,5S,6R)-4-Dimethoxymethyl-5-isopropyl-2-methyl-6-trimethylsilanyloxy-cyclohex-2-enone(187986-23-8)

Safety Data

• Hazardous Substances Data: 187986-23-8(Hazardous Substances Data)

Downstream Products

• 187986-28-3 (1S,2S,6R,8R,10R,11S)-10-(3-chloroperoxybenzoyl)-11-isopropyl-6-methyl-5-methylene-9-oxatricyclo[6.2.1.0^2,6]undecan-7-one 
• 38750-01-5 (1S,2S,6R,8R,11S)-11-isopropyl-6-methyl-5-methylene-9-oxatricyclo[6.2.1.0^2,6]undecan-7,10-dione 
• 2115-91-5 dendrobine 

Relevant articles and documents

Total synthesis of (-)-dendrobine via α-carbonyl radical cyclization

An efficient total synthesis of enantiomerically pure (-)-dendrobine (1) is accomplished based on an α-carbonyl radical cyclization reaction. (S)- carvotanacetone (6) was convened to bicyclic acetal-enone 4 in five steps. Cul-mediated conjugate addition o