18834-21-4Relevant academic research and scientific papers
Hypervalent Hydrosilicates Connected to Light Alkali Metal Amides: Synthesis, Structure, and Hydrosilylation Catalysis
Schuhknecht, Danny,Leich, Valeri,Spaniol, Thomas P.,Okuda, Jun
supporting information, p. 13424 - 13427 (2018/09/06)
When light alkali metal amides [M(Me3TACD)]n (M=Li, Na, K; (Me3TACD)H=1,4,7-trimethyl-1,4,7,10-tetraazacyclododecane) were treated with H2SiPh2 in THF, [M{(H2SiPh2)Me3
Potassium-Catalyzed Hydrosilylation of Activated Olefins: Evidence for a Silyl Migration Mechanism
Leich, Valeri,Spaniol, Thomas P.,Okuda, Jun
supporting information, p. 1179 - 1182 (2016/06/13)
The alkali-metal silyl [K(L)SiPh3] (1; L = 18-crown-6 ether) catalyzed the hydrosilylation of activated C=C double bonds. Isolation and characterization of an addition product is in agreement with the anti-Markovnikov selectivity. Second-order
Hydrosilylation catalysis by an earth alkaline metal silyl: Synthesis, characterization, and reactivity of bis(triphenylsilyl)calcium
Leich, Valeri,Spaniol, Thomas P.,Maron, Laurent,Okuda, Jun
supporting information, p. 2311 - 2314 (2014/03/21)
Bis(triphenylsilyl)calcium [Ca(SiPh3)2(thf)] obtained in high yield as a crystalline ether adduct catalyzes the hydrosilylation of activated C-C double bonds efficiently and regioselectively. The Royal Society of Chemistry 2014.
