188428-40-2

Upstream product

• 186091-03-2 1,2-O-isopropylidene-6-O-benzylhexane-1,2,6-triol 
• 100-39-0 benzyl bromide 
• 106-69-4 hexane-1,2,6-triol 
• 14739-10-7 4-(2,2-dimethyl-1,3-dioxolane-4-yl)-1-butanol 
• 108-24-7 acetic anhydride 
• 71998-68-0 (±)-6-benzyloxyhexan-1,2-diol 

Relevant academic research and scientific papers

Syntheses of spacer-armed carbohydrate model compounds

Commercially available chemicals, such as diethylene glycol, 1,9-nonanediol, 9-decen-1-ol, 1,2,6-hexanetriol, and p-nitrophenol were used to prepare spacer-armed carbohydrate derivatives. Glycosides of D-glucose, N-acetyl-D-glucosamine and 3-O-methyl-D-glucose have been synthesized, carrying reactive groups at the end of the spacer-arms. These glycosides are capable of forming neoglycoproteins. When bromo sugars were reacted with highly apolar aglycones in the presence of mercuric cyanide or mercuric bromide, a considerable amount of '2-OH-compounds' (such as 9-hydroxynonyl 3,4,6-tri-O-acetyl-β-D-glucopyranoside) were formed. Some spacer-armed derivatives (such as 9,10-epoxydecyl β-D-glucopyranoside) are theoretically a mixture of diastereomers, but this fact does not mirror in the 1H and 13C NMR spectra.