1889-63-0

Basic information

• Product Name: S-ETHYL-S-PHENYL SULFOXIMINE
• Synonyms: S-ETHYL-S-PHENYL SULFOXIMINE;Sulfoximine, S-ethyl-S-phenyl-;ethyl(imino)(phenyl)-l6-sulfanone
• CAS NO: 1889-63-0
• Molecular Formula: C₈H₁₁NOS
• Molecular Weight: 169.24
• Mol File: 1889-63-0.mol
• Article Data: 22

Chemical Properties

• Appearance: /
• CAS DataBase Reference: S-ETHYL-S-PHENYL SULFOXIMINE(CAS DataBase Reference)
• NIST Chemistry Reference: S-ETHYL-S-PHENYL SULFOXIMINE(1889-63-0)
• EPA Substance Registry System: S-ETHYL-S-PHENYL SULFOXIMINE(1889-63-0)

Safety Data

• Statements: 22
• Safety Statements: 26-36/37/39
• Hazardous Substances Data: 1889-63-0(Hazardous Substances Data)

Usage

Chemical Properties

Yellow liquid

Upstream product

• 71-23-8 propan-1-ol 
• 1402750-70-2 S-phenyl-S-vinyl-N-ethylsulfoximine 
• 1402750-74-6 (E)-S-phenyl-S-vinyl-N-cinnamylsulfoximine 
• 107-21-1 ethylene glycol 
• 1402750-75-7 S-phenyl-S-vinyl-N-benzylsulfoximine 
• 1402750-76-8 S-phenyl-S-vinyl-N-(4-methoxybenzyl)sulfoximine 
• 1402750-77-9 S-phenyl-S-vinyl-N-(4-bromobenzyl)sulfoximine 
• 1402750-99-5 S-methyl-S-phenyl-N-cinnamylsulfoximine 
• 1202255-11-5 ((4-methoxybenzyl)imino)(methyl)(phenyl)-λ⁶-sulfanone 
• 1402751-01-2 S-methyl-S-phenyl-N-(4-bromobenzyl)sulfoximine 
• 37754-85-1 (N-Benzyl)-methylphenylsulfoximid 
• 4381-25-3 S-methyl-S-phenylsulfoximine 
• 108-98-5 thiophenol 
• 51207-25-1 ethylphenylsulfoxide 

Downstream Products

• 1889-63-0 C₈H₁₁NOS 
• 1377585-55-1 N-[3-(methyl)-benzoyl]-S-ethyl-S-phenylsulfoximine 
• 1584154-63-1 (benzhydrylimino)(ethyl)(phenyl)-λ⁶-sulfanone 
• 67087-37-0 N-methyl-S-ethyl-S-phenylsulfoximine 

Relevant articles and documents

Rhodium(iii)-catalyzed cascade C-H functionalization/annulation of sulfoximines with iodonium ylides for the synthesis of cyclohexanone-1,2-benzothiazines

A highly efficient Rh(iii)-catalyzed cascade C-H activation/annulation of sulfoximines with iodonium ylides under metal-oxidant-free conditions has been reported. The fused cyclohexanone-1,2-benzothiazine scaffold is readily achieved with a one-pot proces

One-Pot Synthesis of N-Iodo Sulfoximines from Sulfides

This is the first report on the synthesis and characterization of N-iodo sulfoximines. The synthesis was designed as a room temperature one-pot cascade reaction from readily available sulfides as starting compounds, converted into sulfoximines by reaction with ammonium carbonate and (diacetoxyiodo)benzene, followed by iodination with N-iodosuccinimide or iodine in situ, in up to 90% isolated yields, also at a multigram scale. Iodination of aryls with N-iodo sulfoximines, oxidation, and conversion to N-SCF3 congeners have been demonstrated.

Sulfoximines Assisted Rh(III)-Catalyzed C-H Activation/Annulation Cascade to Synthesize Highly Fused Indeno-1,2-benzothiazines

A facile access to highly fused tetracyclic indeno-1,2-benzothiazines has been established via a Rh(III)-catalyzed C-H bond activation and intramolecular annulation cascade between sulfoximides and all-carbon diazo indandiones. This strategy is characterized by the fact that the diazo coupling partners do not require preactivation, along with its high efficiency, broad substrate generality, and facile transformation. Particularly, the highly conjugated tetracyclic products demonstrate good optical properties and can easily enter cells to emit bright fluorescence for live cell imaging.