19026-83-6

Basic information

• Product Name: N-(tricyclo[3.3.1.1~3,7~]dec-1-yl)prop-2-enamide
• CAS NO: 19026-83-6
• Molecular Formula: C₁₃H₁₉NO
• Molecular Weight: 205.2961
• Mol File: 19026-83-6.mol
• Article Data: 11

Chemical Properties

• Boiling Point: 367.6°C at 760 mmHg
• Flash Point: 220°C
• Density: 1.08g/cm³
• Vapor Pressure: 1.35E-05mmHg at 25°C
• Refractive Index: 1.542
• CAS DataBase Reference: N-(tricyclo[3.3.1.1~3,7~]dec-1-yl)prop-2-enamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-(tricyclo[3.3.1.1~3,7~]dec-1-yl)prop-2-enamide(19026-83-6)
• EPA Substance Registry System: N-(tricyclo[3.3.1.1~3,7~]dec-1-yl)prop-2-enamide(19026-83-6)

Safety Data

• Hazardous Substances Data: 19026-83-6(Hazardous Substances Data)

Upstream product

• 768-94-5 1-Adamantanamine 
• 79-10-7 acrylic acid 
• 768-95-6 1-adamanthanol 
• 107-13-1 acrylonitrile 
• 768-90-1 1-Adamantyl bromide 
• 814-68-6 acryloyl chloride 
• 79-06-1 2-propenamide 

Downstream Products

• 1354707-97-3 6-(2-((1-adamantyl)carbamoyl)ethyl)-6-nitro-1,4-dibenzylperhydro-1,4-diazepine 

Relevant articles and documents

Switchable hydrogels obtained by supramolecular cross-linking of adamantyl-containing LCST copolymers with cyclodextrin dimers

En route to intelligent hydrogels: Copolymers of N-isopropylacrylamide containing adamantyl groups can be cross-linked noncovalently with cyclodextrin dimers. This results in thermosensitive hydrogels with cloud points that are lower than those of the pure copolymers. Addition of monomeric methylated cyclodextrin results in an increase in the cloud points but has no significant influence on the viscosity of the copolymer solution. (Figure Presented)

Clickable coupling of carboxylic acids and amines at room temperature mediated by SO2F2: A significant breakthrough for the construction of amides and peptide linkages

The construction of amide bonds and peptide linkages is one of the most fundamental transformations in all life processes and organic synthesis. The synthesis of structurally ubiquitous amide motifs is essential in the assembly of numerous important molecules such as peptides, proteins, alkaloids, pharmaceutical agents, polymers, ligands and agrochemicals. A method of SO2F2-mediated direct clickable coupling of carboxylic acids with amines was developed for the synthesis of a broad scope of amides in a simple, mild, highly efficient, robust and practical manner (>110 examples, >90% yields in most cases). The direct click reactions of acids and amines on a gram scale are also demonstrated using an extremely easy work-up and purification process of washing with 1 M aqueous HCl to provide the desired amides in greater than 99% purity and excellent yields.

Tunable white-light emission by supramolecular self-sorting in highly swollen hydrogels

Fluorescence-tunable hydrogels especially emitting white-light were achieved by swelling hydrogels in solutions containing two kinds of dyes. The fluorescence of the dyes was enhanced by the orthogonal supramolecular complexation with different binding si

Microwave assisted, Ca(II)-catalyzed Ritter reaction for the green synthesis of amides

An efficient solvent-free synthesis of amides by Ca(II) catalyzed Ritter reaction has been reported under microwave irradiation. This green protocol tolerates the substrate diversity and delivers the high yielding amides with minimal loading of inexpensive and more abundant Ca(II) catalyst.