190779-62-5

Basic information

• Product Name: 1,3,5-TRIS-(AZIDOMETHYL)-2,4,6-TRIETHYL BENZENE
• Synonyms: 1,3,5-TRIS-(AZIDOMETHYL)-2,4,6-TRIETHYL BENZENE;Benzene, 1,3,5-tris(azidomethyl)-2,4,6-triethyl-
• CAS NO: 190779-62-5
• Molecular Formula: C₁₅H₂₁N₉
• Molecular Weight: 327.38754
• Mol File: 190779-62-5.mol
• Article Data: 18

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 1,3,5-TRIS-(AZIDOMETHYL)-2,4,6-TRIETHYL BENZENE(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3,5-TRIS-(AZIDOMETHYL)-2,4,6-TRIETHYL BENZENE(190779-62-5)
• EPA Substance Registry System: 1,3,5-TRIS-(AZIDOMETHYL)-2,4,6-TRIETHYL BENZENE(190779-62-5)

Safety Data

• Hazardous Substances Data: 190779-62-5(Hazardous Substances Data)

Usage

General Description

1,3,5-TRIS-(AZIDOMETHYL)-2,4,6-TRIETHYL BENZENE, also known as TATB, is a high explosive compound that is commonly used in military and industrial applications. It is a white crystalline powder with a high level of stability and insensitivity to shock, friction, and heat. TATB is often used as a component in plastic bonded explosives (PBXs) due to its high energy and low sensitivity, making it ideal for use in applications where safety and stability are critical. TATB is also used as an ingredient in detonators, boosters, and primers for various military and industrial uses. It is important to handle TATB with extreme care and follow proper safety protocols when working with this compound due to its explosive nature.

InChI:InChI=1/C15H21N9/c1-4-10-13(7-19-22-16)11(5-2)15(9-21-24-18)12(6-3)14(10)8-20-23-17/h4-9H2,1-3H3

Upstream product

• 181058-08-2 1,3,5-tris(bromomethyl)-2,4,6-triethylbenzene 
• 21988-87-4 1,3,5-tris(bromomethyl)-2,4,6-trimethylbenzene 
• 71-43-2 benzene 
• 102-25-0 1,3,5-triethylbenzene 
• 190779-61-4 2,4-bis(bromomethyl)-1,3,5-triethyl benzene 
• 142183-78-6 1,3,5-tris(chloromethyl)-2,4,6-triethylbenzene 

Downstream Products

• 1379690-43-3 C₃₃H₄₈N₁₂O₆ 
• 1379690-40-0 C₂₇H₃₃N₉O₆ 
• 1260113-63-0 C₃₀H₅₄N₆ 
• 1260113-61-8 C₃₀H₄₈N₆O₃ 
• 220472-98-0 Thioacetic acid S-({3,5-bis-[(2-acetylsulfanyl-acetylamino)-methyl]-2,4,6-triethyl-benzylcarbamoyl}-methyl) ester 
• 220472-95-7 2-Mercapto-N-{2,4,6-triethyl-3,5-bis-[(2-mercapto-acetylamino)-methyl]-benzyl}-acetamide 
• 220472-97-9 N-{3,5-Bis-[(2-chloro-acetylamino)-methyl]-2,4,6-triethyl-benzyl}-2-chloro-acetamide 
• 549507-66-6 di-tert-butyl ((5-(aminomethyl)-2,4,6-triethyl-1,3-phenylene)bis(methylene)) dicarbamate 

Relevant articles and documents

Building Covalent Molecular Capsules by Thiol-Michael Addition Click Reaction

The thiol-Michael addition (TMA) is a powerful methodology to click several fragments together, despite having been underestimated in the synthesis of complex systems for supramolecular chemistry. Herein, a very fast and efficient method has been developed to make covalent molecular capsules by taking advantage of the TMA click reaction. Several scaffolds commonly used in supramolecular chemistry, such as calixarenes, CTV, or cavitands, have been used to quickly obtain covalent cages. Additionally, a 'click&click' procedure has been also developed, by sequential combination of TMA and CuAAC click reaction, as an easy and quick way to build complex molecular structures.

Electroactive anion receptor with high affinity for arsenate

Herein, we present the synthesis and characterization of a macrocyclic polyamide cage that incorporates redox-active 1,4-dithiin units. UV/vis titration experiments with eight anions in acetonitrile revealed high affinity for H2AsO4

Alkane oxidation catalysed by a self-folded multi-iron complex

A preorganised ligand scaffold is capable of coordinating multiple Fe(II) centres to form an electrophilic CH oxidation catalyst. This catalyst oxidises unactivated hydrocarbons including simple, linear alkanes under mild conditions in good yields with selectivity for the oxidation of secondary CH bonds. Control complexes containing a single metal centre are incapable of oxidising unstrained linear hydrocarbons, indicating that participation of multiple centres aids the CH oxidation of challenging substrates.