191721-01-4

Upstream product

• 676-58-4 methylmagnesium chloride 
• 162740-21-8 (Z)-N-benzyl-(3-O-benzyl-1,2-O-isopropylidene-α-D-xylofuranos-5-ylidene)amine N-oxide 
• 191721-03-6 (Z)-N-benzyl-(3-O-benzyl-1,2-O-isopropylidene-5-deoxy-α-D-ribofuranos-5-ylidene)amine N-oxide 
• 63593-02-2 3-O-benzyl-1,2-O-isopropylidene-α-D-ribo-pentodialdo-1,4-furanose 
• 23558-05-6 3-O-benzyl-1,2-O-isopropylidene-1,5-D-xylo-dialdofuranose 
• 29601-98-7 N-benzylhydroxylamine hydrochloride 

Downstream Products

• 191721-06-9 3-O-benzyl-5-benzylamino-5,6-dideoxy-1,2-O-isopropylidene-β-L-ido-1,4-furanose 

Relevant academic research and scientific papers

A new route to aminosugars from sugar nitrones: Synthesis of 6-deoxynojirimycin

The 1,3-addition of methylmagnesium chloride to dialdose derived nitrones 3 and 7 afforded N-benzylhydroxylamines 4/5 and 8/9, respectively, in high yields. The stereoselectivity of the addition was improved by the use of trimethylsilyl triflate. The N-O