191721-06-9Relevant academic research and scientific papers
A diastereoselective and general route to 5-amino-5-deoxysugars: Influence of C-3 substitution on the addition of amines to C-5 of vinyl sulfone-modified Hex-5-enofuranosyl carbohydrates
Das, Indrajit,Pathak, Tanmaya,Suresh, Cheravakkattu G.
, p. 8047 - 8054 (2007/10/03)
In the synthesis of vinyl sulfone-modified hex-5-enofuranosides, the E/Z ratios of the products are influenced by the stereoelectronic property of a group present at the C-3 position. This observation has been utilized to influence the diastereoselectivit
A new route to aminosugars from sugar nitrones: Synthesis of 6-deoxynojirimycin
Dhavale, Dilip D.,Desai, Vijaya N.,Sindkhedkar, Milind D.,Mali, Raghao S.,Castellari, Carlo,Trombini, Claudio
, p. 1475 - 1486 (2007/10/03)
The 1,3-addition of methylmagnesium chloride to dialdose derived nitrones 3 and 7 afforded N-benzylhydroxylamines 4/5 and 8/9, respectively, in high yields. The stereoselectivity of the addition was improved by the use of trimethylsilyl triflate. The N-O
