1919-18-2

Basic information

• Product Name: 1,3,5-Triazine, 2,4,6-tris(4-nitrophenoxy)-
• CAS NO: 1919-18-2
• Molecular Formula: C21H12N6O9
• Molecular Weight: 492.361
• Mol File: 1919-18-2.mol
• Article Data: 17

Chemical Properties

• Melting Point: 212-213 °C(Solv: acetic acid (64-19-7))
• Boiling Point: 746.1±70.0 °C(Predicted)
• Density: 1.556±0.06 g/cm3(Predicted)
• CAS DataBase Reference: 1,3,5-Triazine, 2,4,6-tris(4-nitrophenoxy)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3,5-Triazine, 2,4,6-tris(4-nitrophenoxy)-(1919-18-2)
• EPA Substance Registry System: 1,3,5-Triazine, 2,4,6-tris(4-nitrophenoxy)-(1919-18-2)

Safety Data

• Hazardous Substances Data: 1919-18-2(Hazardous Substances Data)

Usage

Structure

Derived from the triazine ring structure with three nitrophenyl groups attached at the 2nd, 4th, and 6th positions.

Industrial applications

a. Building block for polymers, dyes, and pharmaceuticals.
b. Production of herbicides and flame retardants.

Properties

a. High thermal stability.
b. Flame-resistant.

Potential activities

Pesticidal and pharmacological.

Upstream product

• 108-77-0 1,3,5-trichloro-2,4,6-triazine 
• 824-78-2 4-nitrophenol sodium salt 
• 100-02-7 4-nitro-phenol 

Downstream Products

• 108-80-5 isocyanuric acid 
• 100-02-7 4-nitro-phenol 
• 22065-34-5 4,4',4''-((1,3,5-triazine-2,4,6-triyl)tris(oxy))trianiline 
• 1528-74-1 4,4'-dinitrobiphenyl 
• 92-93-3 1-phenyl-4-nitrobenzene 
• 90870-23-8 propyl N-(4-nitrophenyl)carbamate 
• 7506-46-9 N-cyclohexyl-4-nitrobenzamide 
• 2585-26-4 4-nitro-N-benzylbenzamide 
• 89399-20-2 4-nitro-N-pentylbenzamide 
• 98-95-3 nitrobenzene 
• 619-72-7 4-nitrobenzonitrile 
• 13744-88-2 N‐methyl‐N‐(4‐nitrophenyl)benzenamine 
• 836-30-6 4-ntrophenyl(phenyl)amine 
• 4316-57-8 4-nitrophenyldiphenylamine 

Relevant articles and documents

A face-capped [Fe4L4]8+ spin crossover tetrahedral cage

Reported here is a face-capped Fe(ii) molecular tetrahedron, [Fe 4L4](BF4)8, 1. Single crystal X-ray diffraction at 153 and 293 K suggest spin crossover (SCO) and variable temperature magnetic susceptibility measurements confirm 1 displays thermally driven SCO behaviour in the solid state and in dilute acetone solution centred around 284-288 K. The Royal Society of Chemistry 2013.

Nickel-catalyzed reductive amidation of aryl-triazine ethers

The reaction of activated phenolic compounds, 2,4,6-triaryloxy-1,3,5-triazine (aryl-triazine ethers), with various isocyanates or carbodiimides in the presence of a nickel pre-catalyst resulted in the synthesis of aryl amides in good to excellent yields.

Nickel-catalysed C–O bond reduction of 2,4,6-triaryloxy-1,3,5-triazines in 2-methyltetrahydrofuran

A nickel-catalysed reduction of phenol derivatives activated by 2,4,6-trichloro-1,3,5-triazine (TCT) in ecofriendly 2-methyltetrahydrofuran (2-MeTHF) is described. The phenol-TCT derivatives were readily prepared using grinding method in short time without further purification. This catalytic system allowed the facile C–O cleavage of phenol-TCT derivatives under mild reaction conditions with high efficiency and good functional group tolerance. Gram-scale reaction was also achieved. Particularly, sequential functionalization of phenol-TCT derivatives followed by C–O bond reduction could also be realized, affording the high value-added products in moderate to good yields.