35153-45-8Relevant articles and documents
Catalyst-Free and Solvent-Controlled Reductive Coupling of Activated Vinyl Triflates with Chlorotrimethylsilane by Magnesium Metal and Its Synthetic Application
Maekawa, Hirofumi,Noda, Katsuaki,Kuramochi, Keisuke,Zhang, Tianyuan
, p. 1953 - 1956 (2018/04/16)
Vinylsilanes were directly prepared from the corresponding vinyl triflates under magnesium-promoted reductive conditions in THF with no transition metal catalyst, and gem-bis-silylated compounds were obtained in NMP. Investigation of the redox potential o
Studies on the silylation reaction of α,β-epoxy esters synthesized by Darzen's condensation reaction
Bolourtchian, Mohammed,Mamaghani, Manouchehr,Badrian, Abed
, p. 2545 - 2550 (2007/10/03)
Me3SiCl/Mg in HMPA was used for silylation of α,β-epoxy esters resulting in the corresponding β-silylated esters in a one pot reaction with reasonable yields.
Electroreductive silylation of activated olefins using a reactive metal anode
Ohno,Nakahiro,Sanemitsu,Hirashima,Nishiguchi
, p. 5515 - 5516 (2007/10/02)
Electroreductive silylation of α, β-unsaturated esters, nitriles and ketones in the presence of Me3SiCl using a reactive metal anode (Mg, Zn, Al) in an undivided cell afforded the corresponding β-silyl compounds offering a valuable method for introduction of a silyl group into activated olefins.
