1927-62-4Relevant articles and documents
Phosphorus pentoxide as an efficient catalyst for the tetrahydropyranylation of alcohols under solvent-free conditions
Eshghi, Hossein,Shafieyoon, Parvaneh
, p. 2149 - 2152 (2004)
A facile and efficient method for the preparation of tetrahydropyranyl ethers from alcohols is improved in solvent-free media. These reactions are catalyzed by P2O5 and afford various tetrahydropyranyl ethers in shorter reaction time, with good to excellent yields (75-95%) at room temperature. This method is also compatible with substrates containing acid-sensitive functional groups.
2,3-Dichloro-5,6-dicyano-p-benzoquinone as a Mild and Efficient Catalyst for the Tetrahydropyranylation of Alcohols
Tanemura, Kiyoshi,Horaguchi, Takaaki,Suzuki, Tsuneo
, p. 304 - 305 (1992)
Hydroxy compounds readily add to 3,4-dihydro-2H-pyran under neutral conditions in the presence of a catalytic amount of 2,3-dichloro-5,6-dicyano-p-benzoquinone, to give high yields of the corresponding tetrahydropyranyl ethers.
Mild and efficient tetrahydropyranylation of alcohols and dehydropyranylation of THP ethers catalyzed by ferric perchlorate
Heravi, Majid M.,Behbahani, Farahnaz K.,Oskooie, Hossien A.,Shoar, Rahim Hekmat
, p. 2543 - 2545 (2005)
A simple, mild and efficient method for tetrahydropyranylation and dehydropyranylation of alcohols in the presence of ferric perchlorate are described.
Comparison of the efficiency of two dicationic ionic liquids catalysts based on perchloric acid for the protection of alcohols
Rahmanzadeh, Akram,Daneshvar, Nader,Shirini, Farhad,Tajik, Hassan
, p. 3295 - 3302 (2021/05/13)
In this article, two aliphatic and aromatic types of dicationic acidic ionic liquids formulated as [H2-DABCO][ClO4], [H2-Bisim][ClO4]2 were used for the acceleration of the protection of alcohols as t
A facile and versatile electro-reductive system for hydrodefunctionalization under ambient conditions
Huang, Binbin,Guo, Lin,Xia, Wujiong
supporting information, p. 2095 - 2103 (2021/03/26)
A general electrochemical system for reductive hydrodefunctionalization is described, employing the inexpensive and easily available triethylamine (Et3N) as a sacrificial reductant. This protocol is characterized by facile operation, sustainable conditions, and exceptionally wide substrate scope covering the cleavage of C-halogen, N-S, N-C, O-S, O-C, C-C and C-N bonds. Notably, the selectivity and capability of reduction can be conveniently switched by simple incorporation or removal of an alcohol as a co-solvent.
Direct Conversion of TMS-ethers to THP-ethers Catalyzed by {[K.18-Crown-6]Br3}n
Chehardoli, Gholamabbas,Zolfigol, Mohammad Ali,Derakhshanpanah, Fateme
, p. 192 - 197 (2019/04/27)
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