192878-32-3

Basic information

• Product Name: 5-CHLOROTHIENO[2,3-D][1,2,3]THIADIAZOLE-6-CARBOXYLIC ACID
• Synonyms: 5-CHLOROTHIENO[2,3-D][1,2,3]THIADIAZOLE-6-CARBOXYLIC ACID
• CAS NO: 192878-32-3
• Molecular Formula: C5HClN2O2S2
• Molecular Weight: 220.66
• Mol File: 192878-32-3.mol
• Article Data: 3

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 5-CHLOROTHIENO[2,3-D][1,2,3]THIADIAZOLE-6-CARBOXYLIC ACID(CAS DataBase Reference)
• NIST Chemistry Reference: 5-CHLOROTHIENO[2,3-D][1,2,3]THIADIAZOLE-6-CARBOXYLIC ACID(192878-32-3)
• EPA Substance Registry System: 5-CHLOROTHIENO[2,3-D][1,2,3]THIADIAZOLE-6-CARBOXYLIC ACID(192878-32-3)

Safety Data

• Hazardous Substances Data: 192878-32-3(Hazardous Substances Data)

Upstream product

• 67-72-1 hexachloroethane 
• 192878-30-1 thieno[2,3-d][1,2,3]thiadiazole-6-carboxylic acid 
• 97-65-4 2-methylenesuccinic acid 
• 28525-50-0 5-oxotetrahydrothiophene-3-carboxylic acid 
• 192878-28-7 thieno<2,3-d><1,2,3>thiadiazole-6-carboxylic acid methyl ester 
• 192879-23-5 tetrahydro-5-thioxo-3-thiophenecarboxylic acid methyl ester 
• 192879-21-3 tetrahydro-5-oxo-3-thiophenecarboxylic acid methyl ester 
• 100466-79-3 2-[(acetylsulfanyl)methyl]butanedioic acid 
• 28525-49-7 mercaptomethyl-succinic acid 

Relevant articles and documents

Modifying the 5-Position of Thieno[2,3-d][1,2,3]thiadiazole-6-carboxylate Derivatives

Thieno[2,3-d][1,2,3]thiadiazole-6-carboxylates 3 belong to a new group of plant protecting agents as highly potent inducers of systemic acquired resistance (SAR). In order to obtain an enhanced basis set for structure activity relationship studies several

A new type of plant activator: Synthesis of thieno[2,3-d][1,2,3]-thiadiazole-6-carboxylic acid derivatives via Hurd-Mori cyclization

We present a short and efficient synthesis of the title compounds starting with cheap and readily available methylenebutanedioic acid and thioacetic acid. The optimised sequence allows the large-scale preparation of this new type of plant activator in a few steps. ortho-Lithiation is used for the introduction of substituents into the 5-position. A modified reaction mechanism for the Hurd-Mori reaction is suggested to explain the unexpected aromatisation.