192930-86-2

Upstream product

• 75-15-0 carbon disulfide 
• 88223-99-8 L-phenylalanine allyl ester 
• 74-88-4 methyl iodide 

Downstream Products

• 64286-85-7 N-(benzyloxycarbonyl)-L-phenylalanine allyl ester 
• 1161-13-3 N-Cbz-L-Phe 

Relevant academic research and scientific papers

Conversion of carbonimidodithioates to carbamates

Carbonimidodithioates derived from primary amines or α-amino acid esters have been converted to N-benzyloxycarbonyl derivatives under mild conditions by treatment first with sodium benzyl alcoholate and then with water. N-Benzyloxycarbonyl α-amino acids have been generated from the methyl esters by alkaline hydrolysis or from the allyl esters by Pd0-catalysed de-allylation.