19393-45-4

Usage

InChI:InChI=1/C6H7ClO4/c1-10-5(8)3-4(7)6(9)11-2/h3H,1-2H3/b4-3+

Upstream product

• 62173-55-1 dimethyl α,α'-dichloro-succinates 
• 121-69-7 N,N-dimethyl-aniline 
• 7647-01-0 hydrogenchloride 
• 64-19-7 acetic acid 
• 762-42-5 dimethyl acetylenedicarboxylate 
• 67-56-1 methanol 
• 76937-39-8 threo-dimethyl α-fluoro-α'-chlorosuccinate 
• 142-45-0 Acetylenedicarboxylic acid 
• 58175-68-1 C₄H₂Cl₅O₄P 
• 96-02-6 2-chloromaleic anhydride 

Downstream Products

• 118657-83-3 r-3,c-4-bis(methoxycarbonyl)-3-chloro-t-5-methyl-c-5-phenyl-1-pyrazoline 
• 118657-83-3 r-3,c-4-bis(methoxycarbonyl)-3-chloro-c-5-methyl-t-5-phenyl-1-pyrazoline 
• 118657-85-5 1-chloro-cis-1,3-bis(methoxycarbonyl)-2,2-diphenylcyclopropane 
• 118657-85-5 trans-1,3-bis(methoxycarbonyl)-1-chloro-2,2-diphenylcyclopropane 
• 118657-84-4 r-1,t-3-bis(methoxycarbonyl)-1-chloro-t-2-methyl-c-2-phenylcyclopropane 
• 118657-84-4 1-chloro-r-1,c-3-bis(methoxycarbonyl)-c-2-methyl-t-2-phenylcyclopropane 
• 118657-86-6 cis-3,4-bis(methoxycarbonyl)-3-chloro-5,5-diphenyl-1-pyrazoline 

Relevant academic research and scientific papers

Partial Reduction and Selective Transfer of Hydrogen Chloride on Catalytic Gold Nanoparticles

HCl in solution accepts electron density from Au NPs and partially reduces at room temperature, as occurs with other simple diatomic molecules, such as O2 and H2. The activation can be run catalytically in the presence of alkynes to give exclusively E-vinyl chlorides, after the regio- and stereoselective transfer of HCl. Based also on this method, vinyl chloride monomer (VCM) can be produced in a milder and greener way than current industrial processes.

REACTIONS OF CHLORINE MONOFLUORIDE. IV. ADDITION OF CHLORINE MONOFLUORIDE TO HALOGEN-SUBSTITUTED ALKENES

The reactions of chlorine monofluoride with halogenoethylenes (1,1-dichloro-, 1,2-dichloro-, trichloro-, and tetrachloroethylenes) and halogenopropenes ( 3-bromo-, 3,3,3-trichloro-, E- and Z-1,3-dichloro-, 3-chloro-2-methyl-, and perfluoropropenes) were investigated in inert solvents in the presence of ethyl acetate as external nucleophile.In all cases chloroacyloxy adducts were isolated and identified in addition to the chlorofluorination products, and this indicates an electrophilic mechanism for the chlorofluorination of polyhalogenoalkenes.Methyl chloromaleate, chlorofumarate, chlorofluoroethylenedicarboxylate, α,β-difluoroacrylate, and perfluoromethacrylate in anhydrous hydrogen fluoride form the corresponding chlorofluoro adducts with satisfactory yields, whereas the reaction takes place with difficulty in inert solvents.