1942-34-3

Basic information

• Product Name: (1R,2S,5R)-(-)-menthyl (S)-4-methoxyphenylsulfinate
• Synonyms: (1R,2S,5R)-(-)-menthyl (S)-4-methoxyphenylsulfinate
• CAS NO: 1942-34-3
• Molecular Weight: 310.458
• Mol File: 1942-34-3.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: (1R,2S,5R)-(-)-menthyl (S)-4-methoxyphenylsulfinate(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,2S,5R)-(-)-menthyl (S)-4-methoxyphenylsulfinate(1942-34-3)
• EPA Substance Registry System: (1R,2S,5R)-(-)-menthyl (S)-4-methoxyphenylsulfinate(1942-34-3)

Safety Data

• Hazardous Substances Data: 1942-34-3(Hazardous Substances Data)

Upstream product

• 825-90-1 sodium p-hydroxybenzenesulfonate 
• 6462-50-6 sodium 4-methoxybenzenesulfinate 
• 15356-60-2 (1S,2R,5S)-(+)-menthol 
• 31401-23-7 p-methoxybenzenesulfinyl chloride 
• 2216-51-5 (-)-menthol 
• 98-68-0 4-methoxy-phenyl-sulphonyl chloride 
• 696-63-9 4-Methoxybenzenethiol 
• 3724-13-8 p-hydroxybenzenesulfinic acid 
• 4025-67-6 4-hydroxybenzene-1-sulfonyl chloride 
• 1709-60-0 4-methoxybenzenesulfinic acid 
• 77-78-1 dimethyl sulfate 
• 402821-42-5 (-)-(S)-p-hydroxyphenyl menthylsulfinate 

Downstream Products

• 1669-18-7 (R)-p-methoxyphenyl-p-tolylsulfoxide 
• 165035-14-3 (+)-p-Methoxyphenyl-allylsulfoxid 
• 1322750-81-1 (S,E)-1-(4-fluorostyryl)-2-(4-methoxyphenylsulfinyl)benzene 
• 137018-79-2 4'-Octyloxy-biphenyl-4-carboxylic acid 4-((R)-(S)-pentane-2-sulfinyl)-phenyl ester 
• 137018-79-2 4'-Octyloxy-biphenyl-4-carboxylic acid 4-((R)-(R)-pentane-2-sulfinyl)-phenyl ester 
• 129470-37-7 4-Octyloxy-benzoic acid 4-((R)-(S)-pentane-2-sulfinyl)-phenyl ester 
• 129470-36-6 4-Octyloxy-benzoic acid 4-((R)-(R)-pentane-2-sulfinyl)-phenyl ester 
• 129470-28-6 1-Methoxy-4-((R)-(S)-nonane-2-sulfinyl)-benzene 
• 129470-29-7 1-Methoxy-4-((R)-(R)-nonane-2-sulfinyl)-benzene 
• 129470-32-2 4-((S)-Pentane-2-sulfinyl)-phenol 
• 129470-32-2 4-((R)-Pentane-2-sulfinyl)-phenol 
• 129470-34-4 4'-Octyloxy-biphenyl-4-carboxylic acid 4-((R)-(S)-2-methyl-butane-1-sulfinyl)-phenyl ester 
• 129470-42-4 4-((R)-Octane-1-sulfinyl)-phenol 
• 129470-41-3 4-((R)-Pentane-1-sulfinyl)-phenol 

Relevant articles and documents

Chiral cyclopentadienylruthenium sulfoxide catalysts for asymmetric redox bicycloisomerization

A full account of our efforts toward an asymmetric redox bicycloisomerization reaction is presented in this article. Cyclopentadienylruthenium (CpRu) complexes containing tethered chiral sulfoxides were synthesized via an oxidative [3 + 2] cycloaddition reaction between an alkyne and an allylruthenium complex. Sulfoxide complex 1 containing a p-anisole moiety on its sulfoxide proved to be the most efficient and selective catalyst for the asymmetric redox bicycloisomerization of 1,6- and 1,7-enynes. This complex was used to synthesize a broad array of [3.1.0] and [4.1.0] bicycles. Sulfonamide- and phosphoramidate-containing products could be deprotected under reducing conditions. Catalysis performed with enantiomerically enriched propargyl alcohols revealed a matched/mismatched effect that was strongly dependent on the nature of the solvent.

An efficient and novel method for the synthesis of sulfinate esters under solvent-free conditions

The present letter describes a reliable one-stage process for the preparation of sulfinate esters from the corresponding sulfinic acid and alcohols in the presence of N,N′-dicyclohexylcarbodiimide (DCC) under solvent-free conditions.

An improved and efficient procedure for the preparation of chiral sulfinates from sulfonyl chloride using triphenylphosphine

An improved procedure of the Sharpless method for the preparation of chiral sulfinates by triphenylphosphine is described. A mixture of sulfonyl chlorides and diacetone-D-glucose or l-menthol in the presence of triethylamine was treated with triphenylphos