196193-23-4

Upstream product

• 1723-79-1 1-Piperidino-3,7-dimethyl-octadien-(1,3) 
• 78-94-4 methyl vinyl ketone 
• 120093-49-4 (3R)-α-methylene-3,7-dimethyl-6-octen-1-al 
• 105-45-3 acetoacetic acid methyl ester 
• 2385-77-5 (R)-Citronellal 
• 131308-24-2 (2RS,3R)-3,7-Dimethyl-2-(3-oxobutyl)oct-6-enal 

Downstream Products

• 196402-66-1 β-sesquiphellandrene 
• 446018-20-8 (1RS,4RS,1′R)-4-(1′,5′-dimethylhex-4′-enyl)-1-methylcyclohex-2-en-1-ol 
• 915235-16-4 6-hydroxy-4-((R)-6-methylhept-5-en-2-yl)cyclohex-2-enone 
• 159849-08-8 [S-(R*,S*)]-5-(1,5-dimethylhexen-4-yl)-2-methyl-1,3-cyclohexa-1,3-diene 
• 862260-18-2 (24R)-epi-biyouyanagin A 
• 915301-61-0 2-methyl-5-((R)-6-methylhept-5-en-2-yl)cyclohex-3-ene-1,2-diol 
• 1026066-32-9 6-(3-methoxy-4-methyl-phenyl)-2-methyl-hept-2-enoyl chloride 
• 924888-75-5 6-(3-methoxy-4-methyl-phenyl)-2-methyl-hept-2-enoic acid ethyl ester 
• 59684-62-7 (R)-(-)-xanthorrhizol 
• 30199-27-0 (R)-2-methoxy-1-methyl-4-(6-methylhept-5-en-2-yl)benzene 
• 915301-62-1 2-hydroxy-2-methyl-5-((R)-6-methylhept-5-en-2-yl)cyclohex-3-enyl acetate 
• 915235-17-5 2-methyl-5-((R)-6-methylhept-5-en-2-yl)-4-oxocyclohex-2-enyl acetate 
• 915301-63-2 3-methyl-1-(2-methylallyl)-6-((R)-6-methylhept-5-en-2-yl)cyclohex-2-ene-1,4-diol 
• 915235-15-3 4-hydroxy-2-methyl-4-(2-methylallyl)-5-((R)-6-methylhept-5-en-2-yl)cyclohex-2-enone 

Relevant academic research and scientific papers

Zingiberenol, (1 S,4 R,1′ S)-4-(1′,5′-dimethylhex- 4′-enyl)-1-methylcyclohex-2-en-1-ol, identified as the sex pheromone produced by males of the rice stink bug oebalus poecilus (heteroptera: Pentatomidae)

Bioassays using an olfactometer showed that Oebalus poecilus males produce the sexual pheromone, and the chemical analysis demonstrated that this compound is zingiberenol. Two groups of isomers, each containing four diastereoisomers, (1RS,4RS,1′S)- and (1

Identification, synthesis, and bioassay of a male-specific aggregation pheromone from the harlequin bug, Murgantia histrionica

Sexually mature male harlequin bugs produced a sex-specific compound, identified as one of the stereoisomers of the sesquiterpene epoxyalcohol 4-[3-(3,3-dimethyloxiran-2-yl)-1-methylpropyl]-1-methylcyclohex-2-en-1-ol (henceforth murgantiol), a compound wi

Total synthesis and revised structure of biyouyanagin A

(Chemical Equation Presented) It all adds up: A 12-step total synthesis of biyouyanagin A, an inhibitor of HIV replication, has revealed its structure, rendered it available for biological investigations, and allows the synthesis of analogues. The convergent synthesis involves two cascade sequences and a remarkably selective [2+2] cycloaddition reaction to forge the cyclobutane ring of the target molecule in the ultimate step.

Total synthesis of bisabolane sesquiterpenoids, α-bisabol-1-one, curcumene, curcuphenol and elvirol: Utility of catalytic enamine reaction in cyclohexenone synthesis

Total syntheses of α-bisabol-1-one, curcumene, curcuphenol and elvirol have been accomplished via 1,4-conjugate addition of intact aldehydes to vinyl ketones followed by an intramolecular aldol condensation.

Enantiospecific total synthesis of (+)-laevigatin

The first enantiospecific, total synthesis of (+)-laevigatin from (+)-citronellal is described.

Intramolecular Photoaddition of a 1,7-Diene

Intramolecular photoaddition of the 1,7-diene system in 4-(1,5-dimethylhex-4-enyl)cyclohex-2-enone (3) yielded, inter alia, two ketones containing the tricyclo5,11>undecan-8-one system.The structure and stereochemistry of these ketones has been determined from X-ray crystallographic analyses of suitable derivatives.