19620-78-1

Upstream product

• 59547-94-3 diphenyl iodophosphite 
• 108-95-2 phenol 
• 1608-26-0 Hexamethylphosphorous triamide 
• 26546-75-8 phenyl tetramethylphosphorodiamidite 
• 74378-21-5 C-phenylcalix[4]resorcinarene 
• 100649-25-0 C₁₈H₂₈N₃O₂P₂⁽¹⁺⁾*I^(1-) 
• 51-80-9 bis-(dimethylamino)methane 
• 5382-00-3 Diphenyl phosphorochloridite 
• 20502-39-0 Dimethylphosphoramidousdiiodid 
• 139-02-6 sodium phenoxide 

Downstream Products

• 7526-29-6 diphenyl ethylphosphonate 
• 14417-01-7 N,N-dimethylbenzenesulfonamide 
• 934619-27-9 methyl 2-O-benzyl-6-deoxy-6-diphenoxyphosphinyl-3,4-O-isopropylidene-β-D-galactoside 
• 7330-17-8 isopropyl diphenyl phosphite 
• 75944-10-4 O,O-diphenyl N-dimethylamido(tetramethyldiamidophosphorylimido)phosphate 

Relevant academic research and scientific papers

Galactose-derived phosphonate analogues as potential inhibitors of phosphatidylinositol biosynthesis in mycobacteria

Galactose-based phosphonate analogues of myo-inositol-1-phosphate and phosphatidylinositol have been synthesized from methyl β-d- galactopyranoside. Michaelis-Arbuzov reaction of isopropyl diphenyl phosphite or triisopropyl phosphite with a 6-iodo-3,4-iso

Dismutation of arylene phosphorodiamidites: Specific features and aspects of preparative use

The dismutation of arylene phosphorodiamidites derived from the simplest phenols and naphthols and of their dibasic analogs was studied. The main regular trends of this process and the limits of its synthetic applicability were determined. Pleiades Publishing, Inc., 2006.

Dismutation of diamidoarylphosphites

Some examples of spontaneous dismutation of diamidoarylphosphites in different solvents were studied, and features of the process were revealed.

Cyclophosphorylation of polyphenols by diamidoarylphosphites

It was found that the cyclophosphorylation of polyphenols by diamidoarylphosphites proceeds via the rupture of only one P-N bond and one P-O bond, the second P-N bond remaining intact. It is supposed that the unusual lack of reactivity of the P-N bond is due to the spatial arrangement of the amido group with respect to the reaction site in phosphorylated intermediates 5.

INTERACTION OF P(III) COMPOUNDS WITH SILYL HALIDES. THE MECHANISM OF THE REACTION OF PHOSPHOROUS TRIAMIDES WITH TRIALKYLSILYL HALIDES

The reaction of phosphorous hexamethyltriamide with trimethylsilyl iodide or bromide provides a convenient synthesis of the corresponding N,N,N',N'-tetramethylphosphorodiamidous halide.Low temperature (31)P NMR studies gave evidence of the formation of a phosphonium salt-type complex with direct P-Si bonding in the first step of the reaction. Analogous phosphonium salt intermediates involving P-P bonds were found to be involved in some ligand exchange process between two tricoordinated phosphorus species.