19686-79-4Relevant articles and documents
A novel synthesis of 4-cycloheptenones
Marvell, Elliot N.,Titterington, Donald
, p. 2123 - 2124 (1980)
4-Cycloheptenones, mono and bicyclic, can be prepared by a base catalyzed thermal reaction of 1-hepten-6-yn-3-ols.
Enantioselective Synthesis of Tropanes: Br?nsted Acid Catalyzed Pseudotransannular Desymmetrization
Carrillo, Luisa,Merino, Pedro,Reyes, Efraim,Rodriguez, Sandra,Tejero, Tomás,Uria, Uxue,Vicario, Jose L.
, p. 6780 - 6784 (2020/03/19)
The enantioselective synthesis of tropanols has been accomplished through chiral phosphoric acid catalyzed pseudotransannular ring opening of 1-aminocyclohept-4-ene-derived epoxides. The reaction proceeds together with the desymmetrization of the starting
METHOD OF CYCLIC COMPOUNDS PRODUCTION IN OLEFINE METATHESIS REACTION AND USE OF RUTHENIUM CATALYSTS IN PRODUCTION OF CYCLIC OLEFINS IN OLEFINE METATHESIS REACTION
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Page/Page column 62; 63, (2018/11/22)
The invention relates to a method for the preparation of cyclic compounds in the metathesis of olefins from acyclic dienes comprising terminal and/or non-terminal C=C double bonds; the invention also relates to the use of homogeneous ruthenium complexes and homogeneous ruthenium complexes deposited on a solid support as catalysts and/or pre-catalysts for the preparation of cyclic olefins in olefin metathesis reactions. Formula (I)
Precision Polyketones by Ring-Opening Metathesis Polymerization: Effects of Regular and Irregular Ketone Spacing
Arrington, Kyle J.,Murray, Clifton B.,Smith, Emily C.,Marand, Hervé,Matson, John B.
, p. 3655 - 3662 (2016/06/09)
The synthesis and characterization of regioregular aliphatic polyketones is reported. Poly(1-oxoheptamethylene), a semicrystalline polyketone, was prepared via ruthenium-catalyzed ring-opening metathesis polymerization (ROMP) of a ketal-protected 7-membered cyclic ketone followed by subsequent hydrogenation and deprotection. Temperature and catalyst studies of the ROMP reaction guided the preparation of polyketones with high monomer conversions, molecular weights as high as 30 kDa, and dispersities as low as 1.4. Because of the symmetric nature of the monomer, the polymer has ketones spaced every six methylene units apart. The thermal properties of this polyketone were investigated by differential scanning calorimetry, revealing a peak melting range of 160-165 °C. A related polymer, poly(1-oxooctamethylene), was also prepared in a similar fashion, and a peak melting range of only 130-133 °C was observed. This difference in melting range is attributed to the lack of the regioregularity in poly(1-oxooctamethylene), which was derived from an asymmetric 8-membered ring monomer and has ketones spaced every 6, 7, or 8 methylene units apart.