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1,8,8-Trimethyl-3-aza-bicyclo[3.2.1]octane-2,4-dione, also known as 1,8,8-trimethyl-3-azabicyclo[3.2.1]octane-2,4-dione, is a chemical compound with the molecular formula C11H17NO2. It is a white crystalline solid and is commonly used as a chiral auxiliary in organic synthesis, particularly in the preparation of chiral amines and other chiral compounds. 1,8,8-TRIMETHYL-3-AZA-BICYCLO[3.2.1]OCTANE-2,4-DIONE is known for its ability to induce chirality in reactions, making it a valuable tool in the field of asymmetric synthesis. It is also used in the synthesis of various pharmaceuticals and agrochemicals due to its ability to control the stereochemistry of the products formed. The compound is stable and can be stored under normal conditions, but it should be handled with care due to its potential irritant properties.

1972-03-8

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1972-03-8 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 1972-03-8 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 1,9,7 and 2 respectively; the second part has 2 digits, 0 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 1972-03:
(6*1)+(5*9)+(4*7)+(3*2)+(2*0)+(1*3)=88
88 % 10 = 8
So 1972-03-8 is a valid CAS Registry Number.
InChI:InChI=1/C10H15NO2/c1-9(2)6-4-5-10(9,3)8(13)11-7(6)12/h6H,4-5H2,1-3H3,(H,11,12,13)

1972-03-8SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 20, 2017

Revision Date: Aug 20, 2017

1.Identification

1.1 GHS Product identifier

Product name 5,8,8-trimethyl-3-azabicyclo[3.2.1]octane-2,4-dione

1.2 Other means of identification

Product number -
Other names CAMPHORIMIDE

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:1972-03-8 SDS

1972-03-8Relevant academic research and scientific papers

Synthesis of crotonoyl, cynamoyl and p-methoxycynamoyl derivatives of camphoric imide. Crystal and molecular structure of (1R,5S)-3-[(E)-2′-butenoyl]-1,8,8-trimethyl-3-azabicyclo [3.2.1] octane-2,4-dione

Matraszek,Mieczkowski,Cyranski

, p. 477 - 482 (2007/10/03)

Three derivatives of camphoric acid imide (crotonoyl, cynamoyl and p-methoxycynamoyl) have been synthesized. Crystal and molecular structure of (1R,5S)-3-[(E)-2′-butenoyl]-1,8,8-trimethyl-3-azabicyclo[3.2.1]octane-2,4- dione has been determined by X-ray diffraction technique. Crystal data for C14H19NO3: orthorhombic, P212121, a = 10.555 (2) A, b = 11.406 (2) A, c = 11.632 (2) A, Z = 4, R = 0.051 for 4278 reflections. Despite of a small number of heavy atoms, the absolute structure determination occurred to be successful.

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