560-09-8

Usage

Uses

Used in Chiral Surface-Anchored Metal-Organic Frameworks (MOFs):
(1S,3R)-camphoric acid is used as an enantiomeric linker for the preparation of chiral surface-anchored MOFs. Its chiral nature allows for the creation of MOFs with specific structural and functional properties, which can be tailored for various applications.
Used in Porous MOFs for Gas Adsorption and Separation:
(1S,3R)-camphoric acid is utilized in the synthesis of porous MOFs with multifunctional properties. These MOFs are particularly useful in gas adsorption and the separation of racemic alcohols, taking advantage of the chiral properties of the camphoric acid to selectively interact with different molecules.
Used in Coordination Polymers:
(1S,3R)-camphoric acid is a key component in the preparation of a cobalt(II) coordination polymer named Co(phen)(H2O)[C8H14(COO)2]n·(CH3OH)n, where "phen" is 1,10-phenanthroline and C8H14(COOH)2 is [(1S,3R)-camphoric acid]. This coordination polymer has potential applications in various fields, such as catalysis and molecular recognition, due to its unique structural and electronic properties.

InChI:InChI=1/C10H16O4/c1-9(2)6(7(11)12)4-5-10(9,3)8(13)14/h6H,4-5H2,1-3H3,(H,11,12)(H,13,14)/t6-,10+/m0/s1

Upstream product

• 464-45-9 endo-borneol 
• 464-17-5 1,7,7-trimethylbicyclo[2.2.1]hept-2-ene 
• 64474-54-0 (-)-(1S,3R,4R)-3-bromocamphor 
• 7647-01-0 hydrogenchloride 
• 595-32-4 (1R,3R)-1,2,2-Trimethyl-cyclopentane-1,3-dicarboxylic acid 
• 64-19-7 acetic acid 
• 464-48-2 (1S)-camphor 
• 7697-37-2 nitric acid 
• 2767-84-2 (1S,4R)-1,7,7-trimethylbicyclo[2.2.1]heptane-2,3-dione 
• 560-05-4 DL-camphoric acid 

Downstream Products

• 7282-27-1 (1S,3R)-dimethyl 1,2,2-trimethylcyclopentane-1,3-dicarboxylate 
• 26252-16-4 monomethyl ester of (+)-camphoric acid 
• 93740-32-0 ester methylique de l'acide (-)-cis-p-anisoyl-3 trimethyl-1,2,2 cyclopentane carboxylique 
• 93740-43-3 ester methylique de l'acide cis (dimethoxy-2'4' benzoyl)-3 trimethyl-1,2,2 cyclopentane carboxylique 
• 560-07-6 (1S,3S)-(+)-1,2,2-trimethylcyclopentane-1,3-dicarboxylic acid 
• 10333-96-7 1-Bromo-5,8,8-trimethyl-3-oxa-bicyclo[3.2.1]octane-2,4-dione 
• 67111-66-4 (-)-camphanic acid 
• 39637-74-6 (-)-ω-camphanic acid chloride 

Relevant academic research and scientific papers

Sodium percarbonate: A convenient reagent for oxidative cleavage of a-diketones

Sodium percarbonate has been found to be a mild and effective reagent for the oxidative cleavage of a-diketones to carboxylic acids.

Synthesis of 1,11,11-trimethyl-3,6-diazotricyclo [6.2.1.0 2,7]undeca-2,6-diene and 1,15,15-trimethyl-3,10-diazotetracyclo[10.2. 1.02,11.04,9]pentadeca-2,4(9),5,7,10-pentaene from camphoroquinone enantiomers

Optically active camphordihydro-2,3-pyrazine and camphorquinoxaline were prepared from camphoroquinone enantiomers. It was shown that (1S,4R)-(+)-camphoroquinone was formed by oxidation of (1S,3R, 4R)-(-)-3-bromocamphor and (1R,4S)-(-)-camphoroquinone from (1R,3S, 4S)-(+)-3-bromocamphor, respectively. Camphor anhydride was a side product (6-10%) of the reaction. Springer Science+Business Media, Inc. 2007.