560-09-8

Basic information

• Product Name: (1S,3R)-1,2,2-TRIMETHYL-1,3-CYCLOPENTANEDICARBOXYLIC ACID
• Synonyms: (-)-CAMPHORIC ACID, UNNATURAL FORM;(-)-Camphoric acid, (1S,3R)-1,2,2-Trimethyl-1,3-cyclopentanedicarboxylic acid;(1S)-1,2,2-Trimethylcyclopentane-1α,3α-dicarboxylic acid;(1S,3R)-1,2,2-Trimethylcyclopentane-1,3-dicarboxylic acid;[1S,(-)]-1,2,2-Trimethyl-1α,3α-cyclopentanedicarboxylic acid;1,2,2-Trimethylcyclopentane-1α,3α-dicarboxylic acid;Acid, L-caMphor;(1S,3R)-(-)-CaMphoric acid 99%
• CAS NO: 560-09-8
• Molecular Formula: C₁₀H₁₆O₄
• Molecular Weight: 200.23
• EINECS: 200-258-5
• Product Categories: Chiral Compound;Chiral Reagents;Miscellaneous Reagents
• Mol File: 560-09-8.mol
• Article Data: 2

Chemical Properties

• Melting Point: 188-190 °C(lit.)
• Boiling Point: 312°Cat760mmHg
• Flash Point: 156.7°C
• Appearance: /
• Density: 1.177g/cm³
• Vapor Pressure: 0.000119mmHg at 25°C
• Refractive Index: 1.49
• Storage Temp.: Refrigerator
• Solubility: DMSO, Ethanol, Methanol
• PKA: 4.57±0.60(Predicted)
• BRN: 1874674
• CAS DataBase Reference: (1S,3R)-1,2,2-TRIMETHYL-1,3-CYCLOPENTANEDICARBOXYLIC ACID(CAS DataBase Reference)
• NIST Chemistry Reference: (1S,3R)-1,2,2-TRIMETHYL-1,3-CYCLOPENTANEDICARBOXYLIC ACID(560-09-8)
• EPA Substance Registry System: (1S,3R)-1,2,2-TRIMETHYL-1,3-CYCLOPENTANEDICARBOXYLIC ACID(560-09-8)

Safety Data

• Safety Statements: 22-24/25
• WGK Germany: 3
• Hazardous Substances Data: 560-09-8(Hazardous Substances Data)

Usage

Chemical Properties

White Solid

Uses

(1S,3R)-(?)-Camphoric acid can be used:As an enantiomeric linker in the preparation of chiral surface-anchored metal-organic frameworks (MOFs).To prepare porous MOFs having multifunctional properties; used in gas adsorption and separation of racemic alcohols.To prepare a cobalt(II) coordination polymer named {Co(phen)(H2O)[C8H14(COO)2]}n·(CH3OH)n , wherein “phen” is 1,10-phenanthroline and C8H14(COOH)2 is [(1S,3R)-camphoric acid.

InChI:InChI=1/C10H16O4/c1-9(2)6(7(11)12)4-5-10(9,3)8(13)14/h6H,4-5H2,1-3H3,(H,11,12)(H,13,14)/t6-,10+/m0/s1

Upstream product

• 2767-84-2 (1S,4R)-1,7,7-trimethylbicyclo[2.2.1]heptane-2,3-dione 
• 464-48-2 (1S)-camphor 
• 7697-37-2 nitric acid 
• 7647-01-0 hydrogenchloride 
• 595-32-4 (1R,3R)-1,2,2-Trimethyl-cyclopentane-1,3-dicarboxylic acid 
• 64-19-7 acetic acid 
• 64474-54-0 (-)-(1S,3R,4R)-3-bromocamphor 
• 560-05-4 DL-camphoric acid 
• 464-45-9 endo-borneol 
• 464-17-5 1,7,7-trimethylbicyclo[2.2.1]hept-2-ene 

Downstream Products

• 7282-27-1 (1S,3R)-dimethyl 1,2,2-trimethylcyclopentane-1,3-dicarboxylate 
• 560-07-6 (1S,3S)-(+)-1,2,2-trimethylcyclopentane-1,3-dicarboxylic acid 
• 10333-96-7 1-Bromo-5,8,8-trimethyl-3-oxa-bicyclo[3.2.1]octane-2,4-dione 
• 67111-66-4 (-)-camphanic acid 
• 39637-74-6 (-)-ω-camphanic acid chloride 
• 93740-43-3 ester methylique de l'acide cis (dimethoxy-2'4' benzoyl)-3 trimethyl-1,2,2 cyclopentane carboxylique 
• 93740-32-0 ester methylique de l'acide (-)-cis-p-anisoyl-3 trimethyl-1,2,2 cyclopentane carboxylique 
• 26252-16-4 monomethyl ester of (+)-camphoric acid 

Relevant articles and documents

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