198135-77-2Relevant academic research and scientific papers
Novel electrophilic ipso acylation - Detosylation reaction of pyrroles
Pelkey, Erin T.,Gribble, Gordon W.
, p. 1338 - 1342 (2006)
A pyrrole and two pyrroloindoles that are substituted with a p-toluenesulfonyl group undergo an ipso acylation - detosylation reaction with acid chlorides and aluminum chloride to afford the corresponding acyl-substituted pyrroles and pyrroloindoles.
One-step syntheses of the pyrrolo[3,4-b]indole and pyrrolo[2,3-b]indole ring systems from 3-nitroindoles
Pelkey, Erin T.,Gribble, Gordon W.
, p. 1873 - 1874 (2007/10/03)
The reaction of 1-ethoxycarbonyl-3-nitroindole with ethyl isocyanoacetate in the presence of DBU gives ethyl 4-ethoxycarbonyl-2,4-dihydropyrrolo[3,4-b]indole-3-carboxylate, averting a novel rearrangement that we previously reported with 3-nitro-1-phenylsu
