19822-34-5Relevant academic research and scientific papers
A novel synthesis of deactivated benzylic triflones
Goumont, Regis,Faucher, Nicolas,Moutiers, Gilles,Tordeux, Marc,Wakselman, Claude
, p. 691 - 695 (2007/10/03)
A two-step synthesis of benzylic triflones, based on the reaction of 2.4.6-trisubstituted phenyl halides 3a-f with the anion of ethyl (trifluoromethanesulfonyl)acetate 1 followed by a decarboxylation reaction, is reported. The structural assignments are s
TRIFLUOROMETHYLSULFONYL DERIVATIVES OF BENZOFUROXANE AND THEIR ANIONIC ?-COMPLEXES
Yagupol'skii, L. M.,Gogoman, I. V.,Shchupak, G. M.,Boiko, V. N.
, p. 664 - 669 (2007/10/02)
Syntheses are reported for 4-nitro-6-trifluoromethylsulfonyl- and 4,6-bis(trifluoromethylsulfonyl)benzofuroxanes and their anionic ?-complexes with hydroxide and methylate anions.In contrast to its 4,6-dinitro analog, 4,6-bis(trifluoromethylsulfonyl)benzofuroxane forms stable ?-complexes with sodium acetate and sodium azide and has higher acidity by an order of magnitude.
