19826-89-2

Basic information

• Product Name: α-methanesulfonyloxy-p-bromoacetophenone
• Synonyms: α-methanesulfonyloxy-p-bromoacetophenone
• CAS NO: 19826-89-2
• Molecular Weight: 293.138
• Mol File: 19826-89-2.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: α-methanesulfonyloxy-p-bromoacetophenone(CAS DataBase Reference)
• NIST Chemistry Reference: α-methanesulfonyloxy-p-bromoacetophenone(19826-89-2)
• EPA Substance Registry System: α-methanesulfonyloxy-p-bromoacetophenone(19826-89-2)

Safety Data

• Hazardous Substances Data: 19826-89-2(Hazardous Substances Data)

Upstream product

• 10535-17-8 1-(3,4-dimethoxyphenyl)-2-(methoxyphenoxy)propane-1,3-diol 
• 99-73-0 para-bromophenacyl bromide 
• 7382-59-4 guaiacylglycerol-β-guaiacyl ether 
• 99-90-1 para-bromoacetophenone 
• 105551-42-6 (mesyloxyhydroxyiodo)benzene 
• 766-96-1 4-bromo-1-ethynylbenzene 
• 75-75-2 methanesulfonic acid 
• 64-19-7 acetic acid 
• 4203-30-9 1-(4-bromo-phenyl)-2-diazo-ethanone 

Downstream Products

• 65679-14-3 1-(4-bromophenyl)-2-thiocyanatoethanone 

Relevant articles and documents

Straightforward and highly efficient synthesis of α-acetoxy ketones through gold-catalyzed intermolecular oxidation of terminal alkynes

A variety of terminal alkynes were efficiently converted into the corresponding α-acetoxy ketones through gold-catalyzed intermolecular oxidation in the presence of 8-methylquinoline 1-oxide as the oxidant. The reaction probably proceeds through an α-oxo gold carbene intermolecular O-H insertion.

Iodine-mediated α-sulfonyloxylation of alkyl aryl ketones with oxone and sulfonic acids

Alkyl aryl ketones are converted into the corresponding α-sulfonyloxyketones, in moderate to excellent yields, via a novel procedure that utilizes Oxone, p-toluenesulfonic acid or methanesulfonic acid and molecular iodine in a mixture of aceton