1984-28-7Relevant articles and documents
Biphenyl sulfonamide compound and method for preventing and controlling crop pests by using biphenyl sulfonamide compound
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Paragraph 0025; 0094-0095, (2021/10/27)
The invention provides a biphenyl sulfonamide compound or a pesticide pharmacologically acceptable salt thereof, and a method for preventing and treating crop pests by using the biphenyl sulfonamide compound. The biphenyl sulfonamide compound is a compound shown as a formula (I) in the specification. The method for preventing and controlling crop pests comprises the step of applying an effective amount of biphenyl sulfonamide compounds or pharmaceutically acceptable salts thereof to crops so as to control pests harmful to the crops. Surprisingly, the biphenyl sulfonamide compound provided by the invention has excellent prevention and treatment effects on pests, especially armyworms, cabbage caterpillars, small cutworms, beet armyworms, prodenia litura, plutella xylostella, spodoptera litura, corn borers, chilo suppressalis, southern rice borers and the like.
Sulfonyl Azides as Precursors in Ligand-Free Palladium-Catalyzed Synthesis of Sulfonyl Carbamates and Sulfonyl Ureas and Synthesis of Sulfonamides
Chow, Shiao Y.,Stevens, Marc Y.,Odell, Luke R.
, p. 2681 - 2691 (2016/04/26)
(Chemical Equation Presented). An efficient synthesis of sulfonyl carbamates and sulfonyl ureas from sulfonyl azides employing a palladium-catalyzed carbonylation protocol has been developed. Using a two-chamber system, sulfonyl azides, PdCl2, and CO gas, released ex situ from Mo(CO)6, were assembled to generate sulfonyl isocyanates in situ, and alcohols and aryl amines were exploited as nucleophiles to afford a broad range of sulfonyl carbamates and sulfonyl ureas. A protocol for the direct formation of substituted sulfonamides from sulfonyl azides and amines via nucleophilic substitution was also developed.