1985-96-2Relevant articles and documents
Energetics and Dynamics of Radical Pairs in Micelles. Measurement of the Average Singlet-Triplet Energy Gap by means of the Magnetic Field Dependence of 13C CIDNP
Zimmt, Matthew B.,Doubleday, Charles,Turro, Nicholas J.
, p. 3363 - 3365 (1984)
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An electron-deficient diene as ligand for palladium-catalyzed cross-coupling reactions: An efficient alkylation of aryl iodides by primary and secondary alkylzinc reagents
Liu, Qiang,Duan, Hui,Luo, Xiancai,Tang, Yang,Li, Gang,Huang, Rong,Lei, Aiwen
supporting information; experimental part, p. 1349 - 1354 (2009/05/30)
An electron-deficient diene, L1, was found to be an effective ligand in facilitating palladium-catalyzed Negishi couplings involving primary and secondary alkylzinc reagents. The reactions took place readily at 60 °C in THF with 5 mol% of a catalyst generated in situ from bis(acetonitrile) palladium dichloride [PdCl2(MeCN)2] and L1, and functional groups such as chloro, bromo, etc. attached to phenyl ring as well as β-H atoms adjacent to the reaction site were well tolerated. The problematic isomerizations in secondary alkyzinc reagents involved in the reactions reported in the literature were also observed in our system when isopropylzinc chloride was employed alone as the nucleophile. However, the isomerization was significantly suppressed when i-Pr2Zn was utilized in the presence of L1.
Modern Friedel-Crafts Chemistry. Part 24. Alkylation of Benzene with 1,2-Dibromo-3-chloro-2-methylpropane in the Presence of Lewis and Bronsted Acid Catalysts
Albar, Hassan A.,Khalaf, Ali A.,Bahaffi, Saleh O.
, p. 20 - 21 (2007/10/03)
The major alkylation products of benzene with 1,2-dibromo-3-chloro-2-methylpropane are 1-X-2-methyl-3,3-diphenylpropane (X = Cl, Br) with AlCl3 and 1,4-bis-(1-bromo-3-chloro-2-methylpropyl)benzene with AlCl3-CH3NO2 or K10 montmorillonite (K10 Clay); minor products include di- and tri-phenylated butanes and/or 2-methyl-1-phenylindane.