20009-25-0

Basic information

• Product Name: 1-ALLYLOXYNAPHTHALENE
• Synonyms: 1-ALLYLOXYNAPHTHALENE;1-ALLYLOXYNAPHTHALENE 98% [20009-25-0] C13H12O FW184.24;1-[(2-Propenyl)oxy]naphthalene;1-Naphtylallyl ether;Allyl 1-naphtyl ether
• CAS NO: 20009-25-0
• Molecular Formula: C13H12O
• Molecular Weight: 184.23378
• Product Categories: Aromatic Compounds
• Mol File: 20009-25-0.mol
• Article Data: 40

Chemical Properties

• Melting Point: -10 °C (decomp)
• Boiling Point: 307.9 °C at 760 mmHg
• Flash Point: 120.2 °C
• Appearance: /
• Density: 1.048 g/cm³
• Vapor Pressure: 0.00128mmHg at 25°C
• Refractive Index: 1.595
• CAS DataBase Reference: 1-ALLYLOXYNAPHTHALENE(CAS DataBase Reference)
• NIST Chemistry Reference: 1-ALLYLOXYNAPHTHALENE(20009-25-0)
• EPA Substance Registry System: 1-ALLYLOXYNAPHTHALENE(20009-25-0)

Safety Data

• Hazardous Substances Data: 20009-25-0(Hazardous Substances Data)

Usage

General Description

1-ALLYLOXYNAPHTHALENE is a chemical compound consisting of a naphthalene core with an allyloxy group attached to it. It is commonly used in the production of liquid crystal displays and organic light-emitting diodes due to its ability to emit blue light. The allyloxy group enhances the stability and solubility of the compound, making it a valuable component in various electronic applications. Furthermore, 1-ALLYLOXYNAPHTHALENE has also been studied for its potential as a fluorescent probe for detecting certain biological compounds, demonstrating its versatility and potential for various scientific and industrial applications.

InChI:InChI=1/C13H12O/c1-2-10-14-13-9-5-7-11-6-3-4-8-12(11)13/h2-9H,1,10H2

Upstream product

• 90-15-3 α-naphthol 
• 106-95-6 allyl bromide 
• 3019-88-3 sodium naphtholate 
• 3066-75-9 allyl diethyl phosphate 
• 529-34-0 3,4-dihydronaphthalene-1(2H)-one 
• 35466-83-2 allyl methyl carbonate 
• 1838-59-1 3-formyloxy-propene 
• 2216-69-5 1-Methoxynaphthalene 
• 607-58-9 1-(phenylmethoxy)naphthalene 
• 26074-52-2 2-bromo-butyryl bromide 
• 132356-17-3 allyldiisobutyltelluronium bromide 
• 107-05-1 3-chloroprop-1-ene 

Downstream Products

• 2461-42-9 3-(1-naphthyloxy)-1,2-epoxypropane 
• 63972-42-9 2-allyl-1-(benzyloxy)naphthalene 
• 63972-43-0 2-((1-(benzyloxy)naphthalen-2-yl)methyl)oxirane 

Relevant articles and documents

Synthesis and biological evaluation of 7-deoxy analogues of the human rhinovirus 3c protease inhibitor thysanone

The synthesis of (±)-7-deoxythysanone and three analogues has been developed. The key oxa-Pictet-Spengler reaction enabled the synthesis of the naphthopyran precursor, which could be readily converted to 7-deoxythysanone and three related analogues. The biological activity of these compounds was also evaluated against HRV 3C protease, the results of which suggest that inhibition of the enzyme requires the presence of the 7-oxa functionality. Several 7-deoxy analogues of the 3C protease inhibitor thysanone have been synthesised by using an oxa-Pictet-Spengler reaction as the key step. The biological activity of these compounds was also evaluated against human rhinovirus (HRV) 3C protease, the results of which suggest that inhibition of the enzyme requires the presence of the 7-oxa functionality. Copyright

Sharpless asymmetric dihydroxylation of aryloxy allyl ethers: A simple route to chiral β-blockers

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Solid composite copper-copper chloride assisted alkylation of naphthols promoted by microwave irradiation

Naphthyl ethers and naphthyl esters were synthesized in good yield by using mixture of copper metal powder and copper (II) chloride in conventional microwave oven in short time.

Nickel-catalyzed deallylation of aryl allyl ethers with hydrosilanes

An efficient and mild catalytic deallylation method of aryl allyl ethers is developed, with commercially available Ni(COD)2 as catalyst precursor, simple substituted bipyridine as ligand and air-stable hydrosilanes. The process is compatible with a variety of functional groups and the desired phenol products can be obtained with excellent yields and selectivity. Besides, by detection or isolation of key intermediates, mechanism studies confirm that the deallylation undergoes η3-allylnickel intermediate pathway.

Preparation method 3 - phenoxybromopropane or analogue thereof

The invention discloses a preparation method of 3 -phenoxybromopropane or an analogue thereof, wherein 3 - phenoxybromopropane and an allyl compound thereof are obtained through substitution reaction and addition reaction so as to avoid the inconvenience of using gaseous hydrogen bromide, 2nd-step addition reaction is realized by using the brominated salt and the acid in situ, and the process is simple in operation. The condition is easy to control, the atom economy is good, the aspect of environmental impact is low pollution, zero emission accords with the current green chemical synthesis direction, and the cost is economic.

Investigating the microwave-accelerated Claisen rearrangement of allyl aryl ethers: Scope of the catalysts, solvents, temperatures, and substrates

The microwave-accelerated Claisen rearrangement of allyl aryl ethers was investigated, in order to gain insight into the scope of the catalysts, solvents, temperatures, and substrates. Among the catalysts examined, phosphomolybdic acid (PMA) was found to greatly accelerate the reaction in NMP, at temperatures ranging from 220 to 300 °C. This method was found to be useful for preparing several intermediates previously reported in the literature using precious metal catalysts such as Au(I), Ag(I), and Pt(II). Additionally, substrates bearing bromo and nitro groups on the aryl portion required careful tailoring of the reaction conditions to avoid complex product profiles.