200353-85-1

Upstream product

• 64-19-7 acetic acid 
• 1026622-36-5 4-Nitro-benzenesulfonic acid 2-(4-benzyloxy-phenyl)-1-methyl-2-oxo-ethyl ester 
• 127-19-5 N,N-dimethyl acetamide 
• 4495-66-3 4-benzyloxypropiophenone 

Relevant academic research and scientific papers

Synthesis of α-acetoxy and formyloxy ketones by thallium(III) promoted α-oxidation

Treatment of ketones with thallium(III) triflate in amide solvents at 60°C for 30 min followed by addition of small amounts of H2O cleanly provided the corresponding α-acyloxy ketones.

A facile synthesis of secondary α-alkoxy or α-acetoxy aromatic ketones

The treatment of HNIB with aromatic ketones and subsequent solvolysis using alcohol or acetic acid in one-pot system makes it possible to give corresponding secondary α-alkoxy or α-acetoxy ketones in high yields.