201035-87-2

Upstream product

• 40400-15-5 2-(2-iodophenyl)acetonitrile 

Downstream Products

• 944382-73-4 1-[5'-(3''-hydroxy-propan-1''-yl)-2'-furanyl]-2-methylcyano-benzene 
• 944382-57-4 1-[5'-(3''-bromo-propan-1''-yl)-2'-furanyl]-2-(2'''-hydroxybut-3'''-yn-1'''-yl)benzene 
• 201035-88-3 1-[5'-(3''-iodo-propan-1''-yl)-2'-furanyl]-2-(2'''-oxo-but-3'''-yn-1'''-yl)benzene 
• 944382-58-5 1-[5'-(3''-bromo-propan-1''-yl)-2'-furanyl]-2-(2'''-oxo-but-3'''-yn-1'''-yl)benzene 
• 944382-56-3 1-[5'-(3''-bromo-propan-1''-yl)-2'-furanyl]-2-methylcyano-benzene 
• 1027602-12-5 C₁₅H₁₅BrO₂ 

Relevant academic research and scientific papers

Cascade radical-mediated cyclisations with conjugated ynone electrophores. An approach to the synthesis of steroids and other novel ring-fused polycyclic carbocycles

A cascade radical-mediated Diels-Alder reaction with the iododienynone 16b produced the tricyclic ketone 17 (22%). By contrast, treatment of the substituted furans 36 and 47 with Bu3SnH-AIBN, instead led to the tetracycles 44 and 58 respectivel

An exploration of the scope for radical-mediated transannular Diels-Alder reactions in polycycle synthesis

Treatment of the iododienynone 4 with Bu3SnH-AIBN results in the formation of the tricyclic enone 6 by way of radical-mediated macrocyclisation, to 5, followed by transannular Diels-Alder reaction. By contrast, similar treatment of 8 produced t