20115-81-5Relevant articles and documents
Highly efficient synthesis of tetra benzo spiro bis-crown ether
Moradgholi, Fatemeh,Vahedi, Hooshang,Lari, Jalil
, p. 85 - 90 (2015/06/23)
Novel spiro bis-crown ethers derivatives with four benzo units connected via one carbon bridges have been prepared. These compounds represent well preorganized cavities with interesting complexation abilities towards cations. These macrocyclic were prepared by a four-step via template method by utilizing simple precursors catechol, oliethylen glycol and penta erythritol tetra bromide in good yield. Additionally, cesium carbonate could be used as an excellent base for these reactions.
Structural features of a sulfur-containing group 4 metalla[11]-crown-4 derivative
Snell, Alexander,Kehr, Gerald,Wibbeling, Birgit,Fr?hlich, Roland,Erker, Gerhard
, p. 838 - 842 (2007/10/03)
Treatment of the ligand system (o-C6H4OH)-S-CH 2-CH2-S-(o-C6H4-OH) (2a) with TiCl4 gave the metalla-crown ether derivative [(-S-CH 2-CH2-S-)(o-C6
The Stereochemistry of Crown Ethers II -- 1H and 13C NMR Structural Study in Solution
Kleinpeter, E.,Gaebler, M.,Schroth, W.,Mattinen, J.,Pihlaja, K.
, p. 387 - 391 (2007/10/02)
The 1H and 13C NMR spectra of a series of structurally related crown ethers have been recorded, and the signals assigned by means of 1H/13C heteronuclear correlated and 1H/1H homonuclear NOE difference spectroscopy.The NMR parameters so extracted have been used to discuss the preferred, rapidly interconverting solution conformations of the studied species.The high-field shifts in the 13C NMR spectra, within the so-called γ-fragments, and also the 1H/1H homonuclear NOEs, are particularly informative in this respect.The T1 relaxation times of the 13C atoms show segmental motions within the ether segments and suggest different intramolecular flexibilities for the studied compounds.KEY WORDS 1H/13C NMR 2D and 1D NOE difference spectroscopy Crown ethers Conformations in solution Intramolecular flexibility.