201160-28-3

Basic information

• Product Name: (2-methoxyphenyl)(phenyl)(p-tolyl)methanol
• Synonyms: (2-methoxyphenyl)(phenyl)(p-tolyl)methanol
• CAS NO: 201160-28-3
• Molecular Weight: 304.389
• Mol File: 201160-28-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2-methoxyphenyl)(phenyl)(p-tolyl)methanol(CAS DataBase Reference)
• NIST Chemistry Reference: (2-methoxyphenyl)(phenyl)(p-tolyl)methanol(201160-28-3)
• EPA Substance Registry System: (2-methoxyphenyl)(phenyl)(p-tolyl)methanol(201160-28-3)

Safety Data

• Hazardous Substances Data: 201160-28-3(Hazardous Substances Data)

Upstream product

• 134-84-9 4-Methylbenzophenone 
• 33921-62-9 2-Methoxy-phenylmagnesium-jodid 
• 108-88-3 toluene 
• 529-28-2 4-iodoanisol 
• 808-12-8 1,2-bis(4-methylphenyl)-1,2-diphenyl-1,2-ethanediol 
• 98-88-4 benzoyl chloride 

Relevant articles and documents

Sodium-Ketyl Radical Anions by Reverse Pinacol Reaction and Their Coupling with Iodoarenes

Transition-metal-free C-C bond formation between aryl iodides and pinacols is presented. Pinacols are readily transformed by deprotonation with NaH to their Na-pinacolates. C-C-bond homolysis at room temperature generates in situ the corresponding Na-ketyl radical anions which react with various aryl iodides in a homolytic aromatic substitution reaction to form tertiary Na-alcoholates. Protonation eventually provides tertiary alcohols in an unprecedented route.