2023-48-5

Usage

Uses

Used in Organic Synthesis:
Triphenylbismuth Difluoride is used as a catalyst for facilitating a wide range of organic reactions, including carbon-carbon bond formation and other transformations. Its ability to catalyze these reactions makes it a valuable tool in the synthesis of complex organic molecules.
Used in Pharmaceutical Industry:
Triphenylbismuth Difluoride is used as a potential therapeutic agent, particularly in the treatment of cancer. Its unique chemical structure and reactivity may offer new avenues for the development of anticancer drugs.
Used in Antimicrobial Applications:
Triphenylbismuth Difluoride is used as an antimicrobial agent, demonstrating potential in the development of new treatments for bacterial infections. Its ability to target and disrupt microbial processes could lead to the creation of novel antimicrobial therapies.
Used in Materials Science:
Triphenylbismuth Difluoride is used in the development of new polymers and other advanced materials. Its unique properties and reactivity may contribute to the creation of innovative materials with improved performance characteristics for various applications.

InChI:InChI=1/3C6H5.Bi.2FH/c3*1-2-4-6-5-3-1;;;/h3*1-5H;;2*1H/q;;;+2;;/p-2/rC18H15BiF2/c20-19(21,16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15H

Upstream product

• 428-59-1 Hexafluoropropene oxide 
• 47252-14-2 triphenylbismuth carbonate 
• 264607-29-6 triphenylbismuth bis(2,5-dimethylbenzenesulfonate) 
• 7681-49-4 sodium fluoride 
• 28719-54-2 triphenylbismuth dichloride 
• 507233-69-4 triphenyl bismuth ⁽²⁺⁾; dichloride 
• 153289-73-7 triphenylbismuth diformate 

Downstream Products

• 462-06-6 fluorobenzene 
• 603-33-8 triphenylbismuthane 
• 92-52-4 biphenyl 
• 1560-06-1 1-phenyl-2-butene 
• 300-57-2 allylbenzene 
• 501-65-5 diphenyl acetylene 
• 1129-65-3 (hex-1-yn-1-yl)benzene 
• 144479-03-8 1-phenyl-3-benzyloxy-1-propyne 
• 536-74-3 phenylacetylene 
• 2170-06-1 1-Phenyl-2-(trimethylsilyl)acetylene 
• 214141-61-4 mesityltriphenylbismuthonium tetrafluoroborate 
• 214141-63-6 (1-naphtyl)triphenylbismuthonium tetrafluoroborate 
• 30661-62-2 acetonyltriphenylbismuthonium tetrafluoroborate 
• 203342-07-8 (4-methylthiophenyl)triphenylbismuthonium tetrafluoroborate 

Relevant academic research and scientific papers

The use of hexafluoropropene oxide in substitutive fluorination of Sbv and Biv oxygen-containing compounds

Reactions of hexafluoropropene oxide with SbV and BiV oxygen-containing compounds were studied. The E=O (E-O) groups were found to be transformed into the EF2 (E-F) (E = Sb or Bi) groups.

Synthesis and structure of triphenylbismuth difluoride

The reaction of triphenylbismuth dichloride with sodium fluoride in acetone leads to formation of triphenylbismuth difluoride in 73% yield. The X-ray diffraction data show that the bismuth atom in the two symmetrically independent molecules of bismuth dif

Reactions of triarylbismuth bis(arenesulfonates)

Reactions of triphenylbismuth with sodium salts, acids, alkalies, and zinc are studied. In the first three cases Bi-O bond cleavage takes place, while zinc reduces the starting bismuth compounds to triphenylbismuth.

Unexpected Formation of Triarylbismuth Diformates in the Oxidation of Triarylbismuthines with Ozone at Low Temperatures

Oxidation of triphenylbismuthine 1 with ozone in toluene at -78 deg C gave, unexpectedly, a high yield of triphenylbismuth diformate 3, which was also obtainable as a minor product by a similar oxidation in ethyl acetate and acetone.An X-ray crystallographic study revealed that compound 3 has C2 symmetry, the geometry around the bismuth atom being best described as a distorted trigonal bipyramid as a result of strong intramolecular interaction between the bismuth and carbonyl oxygen atoms.Treatment of compound 3 with aqueous sodium acetate or halides readily converted it into the corresponding triphenylbismuth diacetate 5 or dihalides 7 - 9.