203176-35-6

Usage

Uses

Used in Organic Synthesis:
1-(1-Bromovinyl)-2-methoxybenzene is used as a reagent in organic synthesis for its ability to participate in various chemical reactions, contributing to the formation of a wide range of organic compounds.
Used in Chemical Research:
As an intermediate in chemical research, 1-(1-Bromovinyl)-2-methoxybenzene aids in the development and understanding of new chemical processes and reactions.
Used in Pharmaceutical Research:
1-(1-Bromovinyl)-2-methoxybenzene is utilized in pharmaceutical research for its potential role in the synthesis of pharmaceutical compounds, contributing to the discovery of new drugs and therapeutic agents.
Used in the Production of Other Organic Compounds:
This chemical compound serves as a building block in the production of other organic compounds, facilitating the creation of novel materials and substances for various applications across different industries.

Upstream product

• 579-74-8 2-Methoxyacetophenone 
• 767-91-9 1-ethynyl-2-methoxybenzene 
• 74-95-3 1,1-dibromomethane 

Downstream Products

• 103897-42-3 ethyl 4-(2-methoxyphenyl)-4-oxobutanoate 
• 1448165-00-1 1-(2-methoxyphenyl)-2-(phenylsulfonyl)-1-ethanone 

Relevant academic research and scientific papers

Synthesis of Unsymmetrical 1,4-Dicarbonyl Compounds by Photocatalytic Oxidative Radical Additions

Herein we report a photocatalytic oxidative radical addition reaction for the synthesis of unsymmetrical 1,4-dicarbonyl compounds. This reaction utilizes a desulfurization process to generate electrophilic radicals, which add to α-halogenated alkenes and undergo further oxidation to deliver 1,4-dicarbonyl compounds. This mild and highly efficient method provides a valuable alternative to known strategies.

A catalytic allylic cation-induced intermolecular allylation-semipinacol rearrangement

A catalytic intermolecular semipinacol rearrangement induced by allylic carbocations has been realized. This tandem reaction is highly efficient under the catalysis of ZnBr2, generating a wide range of α-homoallyl substituted ketones which contain all-carbon quaternary centres in good to excellent yields (up to 98%) with moderate to high diastereoselectivities (up to >20?:?1). Synthetic application of this novel methodology in the construction of core structures of natural products is also reported.