20364-76-5

Upstream product

• 771-62-0 pentafluorophenylthiol 
• 1600-27-7 mercury(II) diacetate 
• 392-56-3 Hexafluorobenzene 
• 827-15-6 1,2,3,4,5-pentafluoro-6-iodobenzene 
• 27918-31-6 pentafluorobenzenesulfenyl chloride 
• 879-05-0 2,3,4,5,6-pentafluorophenylmagnesium bromide 
• 1076-44-4 pentafluorophenyl lithium 
• 14302-87-5 mercury ion 
• 12596-26-8 dimercury⁽²⁺⁾ 
• 1494-06-0 bis(pentafluorophenyl) disulfide 

Downstream Products

• 1204736-98-0 (C₄H₈O)3Er(SC₆F₅)3 
• 393826-25-0 (CH₃OCH₂CH₂OCH₃)2Er(SC₆F₅)3 
• 393826-18-1 (C₄H₈O)3Ho(SC₆F₅)3 
• 35406-26-9 1,2,3,4,5-Pentafluoro-6-methyldisulfanyl-benzene 
• 35366-49-5 1-Butyldisulfanyl-2,3,4,5,6-pentafluoro-benzene 
• 1043-50-1 pentafluorophenyl sulfide 
• 1204736-97-9 (THF)3Yb(SC₆F₅)3 

Relevant academic research and scientific papers

Fluorinated thiolates of divalent and trivalent lanthanides. Ln-F bonds and the synthesis of LnF3

Fluorinated thiolates from particularly stable chalcogenolate complexes with the lanthanides. Both Sm-(SC6F5)3 and Eu(SC6F5)2 were prepared by transmetalation. The Sm compopund is a dimer in the solid state, with a pair of bridging thiolate ligands connecting the two Sm(III) ions, while the Eu(II) compound is polymeric. In both compounds there are clearly define Ln - F interactions. Thermolysis of the Sm compound gives SmF3 and (C6F4S)n (n = 2, 3, 4).

Heterometallic Ln/Hg compounds with fluorinated thiolate ligands

The early lanthanide benzenefluorothiolates (Ln(SC6F 5)3; Ln = La, Ce, Pr, Nd, Sm, Gd) react with Hg(SC 6F5)2 in DME to form ionic heterometallic compounds with Ln cations and Hg anions. X-ray diffraction analyses of all compounds reveal an isostructural series with the general formula [(DME) 3Ln(SC6F5)2]2[Hg 2(SC6F5)6]. In the structures, a fluorothiolate ligand has been extracted from the Ln coordination sphere that is saturated with three neutral DME donor ligands and a dative interaction between one ortho fluorine and the Ln. Distances between Ln and F do not vary simply with Ln ionic radius. There are two Ln cations with charge balanced by a Hg 2(SC6F5)6 dianion composed of two distinctly nonideal Hg(II) tetrahedra, all connected through a series of π-π interactions that link cations with anions in a one-dimensional array and anions to anions in a more complex 2D network.

Perfluoromethyl element ligands. XLI. [1] compounds of the type (F3C)2EE′R with pseudohalide character (E = P, As; E′ = S, Se, Te)

Perfluoromethyl phosphorus and -arsenic compounds of the type (F3C)2EE′R (E = P, As; E′ = S, Se, Te; R = organic group) are prepared either by dismutation (metathesis) of E2(CF3)4 with (RE′)2/su