203645-98-1

Basic information

• Product Name: [1,1-Biphenyl]-3,5-diol,4-methyl-(9CI)
• Synonyms: [1,1-Biphenyl]-3,5-diol,4-methyl-(9CI)
• CAS NO: 203645-98-1
• Molecular Formula: C₁₃H₁₂O₂
• Molecular Weight: 200.23318
• Product Categories: BIPHENYL
• Mol File: 203645-98-1.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 385.2±22.0 °C(Predicted)
• Appearance: /
• Density: 1.192±0.06 g/cm3(Predicted)
• PKA: 9.29±0.10(Predicted)
• CAS DataBase Reference: [1,1-Biphenyl]-3,5-diol,4-methyl-(9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: [1,1-Biphenyl]-3,5-diol,4-methyl-(9CI)(203645-98-1)
• EPA Substance Registry System: [1,1-Biphenyl]-3,5-diol,4-methyl-(9CI)(203645-98-1)

Safety Data

• Hazardous Substances Data: 203645-98-1(Hazardous Substances Data)

Usage

Description

[1,1-Biphenyl]-3,5-diol,4-methyl-(9CI) is a chemical compound with the molecular formula C13H11O2. It belongs to the class of organic compounds known as biphenyls and derivatives. [1,1-Biphenyl]-3,5-diol,4-methyl-(9CI) is a derivative of biphenyl with a methyl group and hydroxyl groups attached at specific positions. Although it may have various applications in the field of chemistry and materials science, [1,1-Biphenyl]-3,5-diol,4-methyl-(9CI) is not widely studied or used, and its specific properties, applications, and potential hazards are not well-documented.

Upstream product

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• 624-31-7 4-tolyl iodide 
• 203645-96-9 3,5-dimethoxy-4′-methyl-1,1′-biphenyl 
• 5720-05-8 4-methylphenylboronic acid 
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Downstream Products

• 881888-24-0 4-((1R,6R)-6-Isopropenyl-3-methyl-cyclohex-2-enyl)-4'-methyl-biphenyl-3,5-diol 

Relevant articles and documents

Chiral Dinuclear Vanadium Complex-Mediated Oxidative Coupling of Resorcinols

A method for the highly regio- and enantioselective oxidative coupling of resorcinols has been established by using dibrominated dinuclear vanadium(V) catalyst 1c under air. When resorcinols bearing an aryl substituent were applied as substrates to the co

Anti-friedel-crafts-type substitution to form biaryl linkages

The ipso-substitution of one (or two) hydroxy groups of phloroglucinol with arene nucleophiles (e.g., o-xylene, tetralin, biphenyl) can be achieved easily under Friedel-Crafts-type conditions with or without the use of organic solvents affording a variety of 3,5-dihydroxybiphenyls (57-89% yields). The new method has significant practical advantages compared to classical biaryl-coupling routes. Georg Thieme Verlag Stuttgart, New York.

Synthesis of 5-substituted resorcinol derivatives via cross-coupling reactions

Suzuki and Stille cross-coupling reactions were utilized in the synthesis of 5-substituted 1,3-dimethoxybenzerie and 5-substituted resorcinol derivatives. The substituted resorcinol derivatives were obtained in only three steps from inexpensive reagents. 1,3-Dimethoxybenzoic acid and 1-chloro-3,5-dimethoxybenzene were transformed into 1-iodo-, 1-bromo-, 1-trimethyltin-3,5-dimethoxybenzene and 3,5-dimethoxyphenyl boronic acid. 5-Allyl-1,3-dimethoxybenzene and 3,5-dimethoxybiphenyl derivatives were obtained via cross coupling reactions under mild conditions. HI, BBr3 and AlI3 were used to demethylate these dimethoxybenzenes into their resorcinol derivatives.