203806-36-4Relevant academic research and scientific papers
Asymmetric intramolecular aza-Michael reaction using environmentally friendly organocatalysis
Takasu, Kiyosei,Maiti, Soumen,Ihara, Masataka
, p. 51 - 55 (2007/10/03)
This communication describes enantioselective intramolecular aza-Michael reaction to prepare 1,2,3,4-tetrahydroisoquinolines by using organocatalysts. The organocatalytic reaction offers new green chemical process in heterocyclic chemistry. Additional not
Stereoselective isoquinoline alkaloid synthesis with new diselenides
Wirth, Thomas,Fragale, Gianfranco
, p. 162 - 166 (2007/10/03)
The synthesis of improved optically active selenium compounds for electrophilic additions to C=C double bonds is described. These reagents allow the formation of methoxyselenenylated products with high diastereoselectivities (up to 93% de). Intramolecular aminoselenenylations with chiral selenium electrophiles provide a short route to tetrahydroisoquinoline alkaloids.
