204135-21-7Relevant articles and documents
9,10-Dimetallatriptycenes of group 14: A structural study
Dam, Matheus A.,De Kanter, Franciscus J. J.,Bickelhaupt, Friedrich,Smeets, Wilberth J. J.,Spek, Anthony L.,Fornies-Camer, Jorge,Cardin, Christine
, p. 347 - 353 (1998)
From ortho-phenylenemagnesium (1), 9-phenyl-9-germa-10-silatriptycene (5) was prepared via a simple one pot procedure. The previously prepared 9-methyl-10-phenyl-9,10-digermatriptycene (4) and 5 are the first germanium-containing 9,10-dimetallatriptycenes to be structurally characterised. The availability of these structural data allows a comparative discussion of 9,10-dimetallatriptycenes of Group 14.