10-phenyl-9,10-dihydro-10-germa-9-sila-9,10[1',2']-benzenoanthracene

Base Information

Chemical Name:10-phenyl-9,10-dihydro-10-germa-9-sila-9,10[1',2']-benzenoanthracene
CAS No.:204135-21-7
Molecular Formula:C₂₄H₁₈GeSi
Molecular Weight:407.082
Hs Code.:

Synonyms:10-phenyl-9,10-dihydro-10-germa-9-sila-9,10[1',2']-benzenoanthracene

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Chemical Property of 10-phenyl-9,10-dihydro-10-germa-9-sila-9,10[1',2']-benzenoanthracene

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Technology Process of 10-phenyl-9,10-dihydro-10-germa-9-sila-9,10[1',2']-benzenoanthracene

There total 1 articles about 10-phenyl-9,10-dihydro-10-germa-9-sila-9,10[1',2']-benzenoanthracene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: 10025-78-2
trichlorosilane

: 1074-29-9
trichlorophenylgermane

: 204135-21-7
10-phenyl-9,10-dihydro-10-germa-9-sila-9,10[1',2']-benzenoanthracene

Guidance literature:: With ortho-phenylenemagnesium; In tetrahydrofuran; toluene; benzene; absence of air and moisture; slow addn. of Ge-compd. (in PhMe) to excessof Mg-compd. (in THF) at -15°C, stirring (-15°C, 2 h), sl ow addn. of equimolar amt. of Si-compd. (in C6H6), stirring (-15°C, 2 h, 5°C, 1 h); warming to room temp. overnight, quenching with satd. NH4Cl, extn. into PhMe, drying of org. layer (MgSO4), filtration, evapn. (vac.), dissoln. in C6H6, chromy. (SiO2, C6H6), evapn., recrystn. (PhMe);
DOI:10.1016/S0022-328X(97)00237-4

Reference yield: 70.0%

: 204135-21-7
10-phenyl-9,10-dihydro-10-germa-9-sila-9,10[1',2']-benzenoanthracene

: 591-51-5
phenyllithium

: 263772-61-8
9,10-diphenyl-9,10-dihydro-10-germa-9-sila-9,10[1'2']benzenoanthracene

Guidance literature:: With NH₄Cl; In diethyl ether; cyclohexane; under argon, Schlenk setup, 1:6 mixt., after 1 min satd. NH4Cl soln. added; extd. (CHCl3), filtered, dried (MgSO4), evapd., washed (Et2O), elem. anal.;
DOI:10.1021/om990976o

Reference yield: 65.0%

: 204135-21-7
10-phenyl-9,10-dihydro-10-germa-9-sila-9,10[1',2']-benzenoanthracene

: 205237-27-0
9-ethylnyl-10-phenyl-9,10-dihydro-9,10-digerma-9,10[1',2']-benzenoanthracene

: trans-1-(9-(10-phenyl-9,10-digermatriptycyl))-2-(9-(10-phenyl-10-germa-9-silatriptycyl))ethene

Guidance literature:: With air; dihydrogen hexachloroplatinate(IV) hexahydrate; In tetrahydrofuran; air bubbling (5 min), stirring (room temp., 18 h); decanting, washing (THF), evapn. (vac.), chromy. (SiO2, CHCl3), evapn., washing (C6H6), drying (vac.); elem. anal.;
DOI:10.1021/om980073f