20459-96-5Relevant academic research and scientific papers
DIENCARBONSAEUREN AUS 1,3-DIENEN UND CO2 DURCH C-C-VERKNUEPFUNG AN NICKEL(0)
Hoberg, H.,Schaefer, D.,Oster, B. W.
, p. 313 - 320 (1984)
(Lig)Ni0 systems react with 1,3-dienes in the presence of CO2 to give nickela carboxylates.The influence of ligands and temperature on the regioselectivity of the C-C bond formation is elucidated.In some cases the nickela carboxylates undergo reductive elimination under the influence of maleic anhydride, and the coupled diene/CO2 moiety rearranges to give the diene carboxylic acid.A possible reaction sequence is discussed.
