Journal of Organometallic Chemistry p. 313 - 320 (1984)
Update date:2022-08-05
Topics:
Hoberg, H.
Schaefer, D.
Oster, B. W.
(Lig)Ni0 systems react with 1,3-dienes in the presence of CO2 to give nickela carboxylates.The influence of ligands and temperature on the regioselectivity of the C-C bond formation is elucidated.In some cases the nickela carboxylates undergo reductive elimination under the influence of maleic anhydride, and the coupled diene/CO2 moiety rearranges to give the diene carboxylic acid.A possible reaction sequence is discussed.
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