2046-33-5Relevant articles and documents
Diverse meta-C?H Functionalization of Arenes across Different Linker Lengths
Jayarajan, Ramasamy,Das, Jayabrata,Bag, Sukdev,Chowdhury, Rajdip,Maiti, Debabrata
, p. 7659 - 7663 (2018)
Arenes containing conformationally flexible long alkyl chains have been successfully functionalized at the meta-position. Good to excellent meta selectivity is achieved for systems with up to 20 atoms between the target C?H bond and the coordinating heter
Remarkably high catalyst efficiency of a disilaruthenacyclic complex for hydrosilane reduction of carbonyl compounds
Tahara, Atsushi,Sunada, Yusuke,Takeshita, Takashi,Inoue, Ryoko,Nagashima, Hideo
supporting information, p. 11192 - 11195 (2018/10/24)
A disilaruthenacyclic complex (1) showed extremely high catalytic activity for hydrosilane reduction of aldehydes and ketones to silyl ethers and secondary and tertiary amides to the corresponding amines. An σ-CAM mechanism was proposed to explain the activity.
Single-Electron-Transfer-Induced Coupling of Alkylzinc Reagents with Aryl Iodides
Okura, Keisho,Shirakawa, Eiji
, p. 3043 - 3046 (2016/07/14)
Alkylzinc reagents prepared from an alkyllithium and zinc iodide were found to undergo coupling with aryl and alkenyl iodides in the presence of LiI in a mixed solvent consisting of THF and diglyme (1:1). Alkyllithiums, prepared by halogen–lithium exchange between an alkyl iodide and tert-butyllithium, are also converted to alkylarenes through alkylzinc reagents.