2049-52-7Relevant academic research and scientific papers
Cathodic Reduction of 1,2-Dibenzoylchloroethane. Formation of Cyclic Dimolecular Products
Barba, Fructuoso,Fuente, Jose Luis de la
, p. 7685 - 7687 (2007/10/02)
The electrochemical reduction of 1,2-dibenzoylchloroethane in aprotic medium (DMF-LiClO4) on mercury cathode gives four dimeric products.Two of them correspond to cyclic structures, 1-phenyl-c-2,t-3,c-4-tribenzoyl-r-1-cyclopentanol (41-43percent) and 1-phenyl-c-2,c-3,t-4-tribenzoyl-r-1-cyclopentanol (16-18percent), and the other two were identified as the racemic and meso 1,6-diphenyl-3,4-dibenzoyl-1,6-butanediones (24-26 and 8-10percent, respectively).The dehydration of these products leads to the formation of furans, bisfurans, or cyclopentenes depending on the experimental conditions.
