206348-92-7

Basic information

• Product Name: (S)-1-hydroxypent-4-en-2-yl benzoate
• Synonyms: (S)-1-hydroxypent-4-en-2-yl benzoate
• CAS NO: 206348-92-7
• Molecular Weight: 206.241
• Mol File: 206348-92-7.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: (S)-1-hydroxypent-4-en-2-yl benzoate(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-1-hydroxypent-4-en-2-yl benzoate(206348-92-7)
• EPA Substance Registry System: (S)-1-hydroxypent-4-en-2-yl benzoate(206348-92-7)

Safety Data

• Hazardous Substances Data: 206348-92-7(Hazardous Substances Data)

Upstream product

• 2100-17-6 4-pentenal 
• 94-36-0 dibenzoyl peroxide 
• 206348-89-2 Chloro-acetic acid (S)-1-[dimethyl-(1,1,2-trimethyl-propyl)-silanyloxymethyl]-but-3-enyl ester 
• 206348-90-5 (S)-1-[Dimethyl-(1,1,2-trimethyl-propyl)-silanyloxy]-pent-4-en-2-ol 
• 206348-79-0 1-[Dimethyl-(1,1,2-trimethyl-propyl)-silanyloxy]-pent-4-en-2-ol 
• 157920-22-4 2-hydroxy-pent-4-enoic acid ethyl ester 
• 103625-11-2 (±)-pent-4-en-1,2-diol 
• 223429-12-7 (1S,2R,4S,6S,7R)-4-((S)-1-Benzoyloxy-but-3-enyl)-7,10,10-trimethyl-3-oxa-5-aza-tricyclo[5.2.1.0^2,6]decane-5-carboxylic acid tert-butyl ester 
• 206348-91-6 Benzoic acid (S)-1-[dimethyl-(1,1,2-trimethyl-propyl)-silanyloxymethyl]-but-3-enyl ester 

Relevant articles and documents

Direct Asymmetric Benzoyloxylation of Aldehydes Catalyzed by 2-Tritylpyrrolidine

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Diphenylprolinol silyl ether as a catalyst in an asymmetric, catalytic and direct α-benzoyloxylation of aldehydes

Diphenylprolinol silyl ether was found to promote asymmetric, catalytic and direct α-benzoyloxylation of aldehydes with benzoyl peroxide to afford oxidized products in good yields with excellent enantioselectivity. The Royal Society of Chemistry 2009.

Chemoenzymatic synthesis of glycosylated enantiomerically pure 4- pentene 1,2- and 1,3-diol derivatives

1-Dimethylthexylsiloxy-2-chloroacetoxy-4-pentene 2 and 1- dimethylthexylsiloxy-3-chloroacetoxy-4-pentene 3 were saponified with Pseudomonas lipase to give (R)-1-dimethylthexylsiloxy-4-pentene-2-ol (ee=99%) and (S)-2 (ee=99%) and (S)-1-dimethylthexylsiloxy