80596-05-0

Basic information

• Product Name: methyl O-(2-O-acetyl-3,4,6-tri-O-benzyl-α-D-mannopyranosyl)-(1<*>2)-3,4,6-tri-O-benzyl-α-D-mannopyranoside
• Synonyms: methyl O-(2-O-acetyl-3,4,6-tri-O-benzyl-α-D-mannopyranosyl)-(1<*>2)-3,4,6-tri-O-benzyl-α-D-mannopyranoside
• CAS NO: 80596-05-0
• Molecular Weight: 939.112
• Mol File: 80596-05-0.mol

Chemical Properties

• CAS DataBase Reference: methyl O-(2-O-acetyl-3,4,6-tri-O-benzyl-α-D-mannopyranosyl)-(1<*>2)-3,4,6-tri-O-benzyl-α-D-mannopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: methyl O-(2-O-acetyl-3,4,6-tri-O-benzyl-α-D-mannopyranosyl)-(1<*>2)-3,4,6-tri-O-benzyl-α-D-mannopyranoside(80596-05-0)
• EPA Substance Registry System: methyl O-(2-O-acetyl-3,4,6-tri-O-benzyl-α-D-mannopyranosyl)-(1<*>2)-3,4,6-tri-O-benzyl-α-D-mannopyranoside(80596-05-0)

Safety Data

• Hazardous Substances Data: 80596-05-0(Hazardous Substances Data)

Upstream product

• 20672-67-7 methyl 3,4,6-tri-O-benzyl-α-D-mannopyranoside 
• 65827-59-0 2-O-acetyl-3,4,6-tri-O-benzyl-α-D-mannopyranosyl chloride 
• 93381-69-2 2-O-acetyl-3,4,6-tri-O-benzyl-α-D-mannopyranosyl bromide 
• 130525-72-3 ethyl 2-O-acetyl-3,4,6-tri-O-benzyl-1-thio-α-D-mannopyranoside 
• 20672-69-9 methyl 2-O-acetyl-3,4,6-tri-O-benzyl-α-D-mannopyranoside 
• 68681-00-5 3,4,6-tri-O-benzyl-1,2-O-<1-(R)-methoxyethylidene>-β-D-mannopyranose 
• 16697-49-7 3,4,6-tri-O-benzyl-1,2-O-(methoxyethylidene)-β-D-mannopyranose 
• 138181-67-6 phenyl 2-O-acetyl-3,4,6-tri-O-benzyl-1-thio-α-D-mannopyranoside 
• 124684-91-9 2-O-acetyl-3,4,6-tri-O-benzyl-1-deoxy-α-D-mannopyranosyl fluoride 
• 108869-64-3 2-O-acetyl-3,4,6-tri-O-benzyl-α-D-mannopyranosyl trichloroacetimidate 
• 129214-38-6 2-O-acetyl-3,4,6-tri-O-benzyl-D-mannopyranoside 

Downstream Products

• 80585-62-2 methyl O-(3,4,6-tri-O-benzyl-α-D-mannopyranosyl)-(1<*>2)-3,4,6-tri-O-benzyl-α-D-mannopyranoside 

Relevant articles and documents

Synthesis of tri- and tetra-mannosides based on sequential one-pot three-component glycosylation reactions

Expeditious syntheses of tri- and tetra-mannosides were carried out based on sequential one-pot glycosylation strategy. In both of these syntheses TMSOTf activated trichloroacetimidate, the first glycosyl donor, and inexpensive readily accessible trichlor

Mannose-binding geometry of pradimicin A

Pradimicins (PRMs) and benanomicins are the only family of non-peptidic natural products with lectin-like properties, that is, they recognize D-mannopyranoside (Man) in the presence of Ca2+ ions. Coupled with their unique Man binding ability, t

A three-component, one-pot, sequential synthesis of a common tetrasaccharide block related to the lipopolysaccharide of the Escherichia Coli O9, Klebsiella pneumonia O3, and Hafnia alvei PCM 1223

An expeditious three-component, one-pot, sequential synthesis of a common block tetrasaccharide fragment Manp-(1→3)-Manp-(1→2)-Manp-(1→2)- Manp related to the pentasaccharide repeating unit of the O-antigen of Escherichia Coli O9, Klebsiella pneumonia O3, and Hafnia alvei PCM 1223 with minimal protecting group manipulation is reported. Georg Thieme Verlag Stuttgart · New York.

Sonication-assisted oligomannoside synthesis

We have investigated the use of sonication for the synthesis of oligomannosides. A convenient sonication- mediated glycosylation protocol that is applicable to traditional glycosylation methods has been developed. This protocol can be applicable for activ

Synthesis of the repeating trisaccharide unit of the cell wall lipopolysaccharide of Escherichia coli type 8

NIS/TfOH mediated glycosidation of methyl 3,4,6-tri-O-benzyl-α-d-mannopyranoside with phenyl 2-O-acetyl-3,4,6-tri-O-benzyl-1-thio-α-d-mannopyranoside furnished the corresponding disaccharide derivative in excellent yield and α-selectivity. Ze?mplen deacet

Synthesis of oligosaccharide substrates for N-linked glycoprotein processing enzymes

The stereoselective syntheses of one pentasaccharide and one tetrasaccharide containing the Glc-α-(1 → 3)-Man-α moiety as their terminal unit, as well as one tetrasaccharide and one trisaccharide containing the Man-α-(1 → 2)-Man-α terminal unit were accomplished through the utilization of two key glycosyl donors, namely, 4-pentenyl 3-O-acetyl-2,4,6-tri-O-benzyl-α-D-mannopyranoside and ethyl 2-O-acetyl-3,4,6-tri-O-benzyl-1-thio-α-D-mannopyranoside.

Synthesis and Conformational Analysis of Methyl 2-O-(α-D-Mannopyranosyl)-α-D-mannopyranoside

NMR experiments such as steady state NOE experiments and spin lattice 1H relaxation time measurements were performed on the synthetic disaccharide 10 that constitutes part of the polysaccharide backbone in fungal mannans.The spectroscopic data were compar

SYNTHETIC STUDIES ON CELL SURFACE GLYCANS 3 BRANCHING PENTASACCHARIDES OF GLYCOPROTEIN

Synthetic routes for the branching pentasaccharides 4 and 5 of glycoproteins are described in a regio- and stereo-controlled way.